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Malonic acid overset(P(2)O(5))underset...

Malonic acid
`overset(P_(2)O_(5))underset(150^(@)C)rarr" Foul smell"(A)overset(200^(@)C)rarr(B)+"Carbon"`
The total number of `sigma` and `P i` bonds present in compound A are :

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To solve the problem, we need to determine the total number of sigma (σ) and pi (π) bonds present in compound A, which is formed from malonic acid under specific conditions. ### Step 1: Identify the structure of malonic acid Malonic acid has the molecular formula \( C_3H_4O_4 \) and can be represented as: \[ \text{HOOC-CH}_2\text{-COOH} \] ### Step 2: Determine the reaction conditions When malonic acid reacts with \( P_2O_5 \) at \( 150^\circ C \), it produces a compound with the formula \( C_3O_2 \) (which is compound A) and phosphoric acid \( H_3PO_4 \). ### Step 3: Identify the structure of compound A The compound \( C_3O_2 \) can be represented as: \[ \text{O=C=C=O} \] This structure indicates that there are two carbon atoms double bonded to an oxygen atom and one carbon atom double bonded to another oxygen atom. ### Step 4: Count the sigma bonds In the structure of \( C_3O_2 \): - Each carbon-carbon bond is a sigma bond. - Each carbon-oxygen bond is also a sigma bond. For \( C_3O_2 \): - There are 2 carbon-carbon bonds (C=C). - There are 2 carbon-oxygen bonds (C=O). Thus, the total number of sigma bonds is: \[ \text{Number of σ bonds} = 2 \text{ (C=C)} + 2 \text{ (C=O)} = 4 \] ### Step 5: Count the pi bonds In the structure of \( C_3O_2 \): - Each double bond consists of one sigma bond and one pi bond. For \( C_3O_2 \): - There are 2 double bonds (C=C and C=O). Thus, the total number of pi bonds is: \[ \text{Number of π bonds} = 2 \text{ (C=C)} + 2 \text{ (C=O)} = 4 \] ### Step 6: Calculate the total number of σ and π bonds Now, we can find the total number of sigma and pi bonds in compound A: \[ \text{Total number of σ and π bonds} = \text{Number of σ bonds} + \text{Number of π bonds} = 4 + 4 = 8 \] ### Final Answer The total number of sigma and pi bonds present in compound A is **8**. ---
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