Home
Class 12
CHEMISTRY
A compound with molecular mass 180 is ac...

A compound with molecular mass 180 is acylated with `CH_(3)COCl` to get a compound with molecular mass 390. the number of amino groups present per molecule of the former compound is-

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the number of amino groups present in a compound with a molecular mass of 180 after it is acylated with acetic chloride (CH₃COCl) to yield a compound with a molecular mass of 390. ### Step-by-Step Solution: 1. **Identify the Initial and Final Molecular Masses**: - The initial compound has a molecular mass of 180 g/mol. - After acylation with CH₃COCl, the final compound has a molecular mass of 390 g/mol. 2. **Calculate the Change in Molecular Mass**: - The change in molecular mass due to acylation can be calculated as: \[ \text{Change in mass} = \text{Final mass} - \text{Initial mass} = 390 \, \text{g/mol} - 180 \, \text{g/mol} = 210 \, \text{g/mol} \] 3. **Determine the Mass Increase per Amino Group**: - When an amino group (NH₂) is acylated, it is converted to an acylated amino group (NHCOCH₃). The mass change for one NH₂ group can be calculated as follows: - Mass of NH₂ = 14 (N) + 2 (H) = 16 g/mol - Mass of NHCOCH₃ = 14 (N) + 1 (C) + 3 (H from CH₃) + 16 (O) = 58 g/mol - Therefore, the increase in mass per acylation is: \[ \text{Increase} = \text{Mass of NHCOCH₃} - \text{Mass of NH₂} = 58 \, \text{g/mol} - 16 \, \text{g/mol} = 42 \, \text{g/mol} \] 4. **Calculate the Number of Amino Groups**: - Now, we can find the number of amino groups (n) in the original compound by dividing the total mass increase by the mass increase per amino group: \[ n = \frac{\text{Total mass increase}}{\text{Mass increase per amino group}} = \frac{210 \, \text{g/mol}}{42 \, \text{g/mol}} = 5 \] 5. **Conclusion**: - Therefore, the number of amino groups present per molecule of the former compound is **5**.
Promotional Banner

Similar Questions

Explore conceptually related problems

An organic compound A ( mol wt = 180) is acylated with CH_3 COCl to get acylated compound of mol wt. 390. What is the number of amino groups present per molecule of the compound A?

Number of functional groups present in the following compound is :

Number of functional groups present in the following compound is :

A compound of mol wt. 180 is acetylated to give a compound of molecular wt. 390. What is the number of amine in the initial compounds?

An oxide of nitrogen has a molecular weight of 30. Total number of electrons in one molecule of the compound is

The empirical formula of a compound of molecular mass 120 is CH_(2)O . The molecular formula of the compound is :

Amines are basic in nature and show many types of reactions such as substitution, Hoffmann elimination, carbylamine, acylation, diazotisation etc. Certain nitrogeneous compound with molecular mass 180 shows an increase in its molecular mass to 348 after treatment with acetyl chloride. The number of possible - NH_(2) groups in the molecule is...................

A compound with molecular formula C_(6)H_(10)O_(4) on acylation with acetic anhydride gives a compound with molecular formula C_(12)H_(18)O_(8) . How many hydroxyl groups are present in the compound?

An organic compound 'A' having molecular formula C_(5)H_(10)O_(6) on acetylation forms a compound having molecular weight 334. Number of hydroxy group (-OH) in the compound 'A' is: