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The spin only magnetic moment of transit...

The spin only magnetic moment of transition metal ion found to be 5.92 BM. The number of unpaired electrons present in the species is :

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To solve the problem of determining the number of unpaired electrons in a transition metal ion given its spin-only magnetic moment of 5.92 Bohr magnetons (BM), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Formula**: The formula for calculating the spin-only magnetic moment (μ) in terms of the number of unpaired electrons (n) is given by: \[ \mu = \sqrt{n(n + 2)} \] 2. **Substitute the Given Value**: We know that the magnetic moment (μ) is 5.92 BM. We can substitute this value into the formula: \[ 5.92 = \sqrt{n(n + 2)} \] 3. **Square Both Sides**: To eliminate the square root, we square both sides of the equation: \[ (5.92)^2 = n(n + 2) \] Calculating \(5.92^2\): \[ 5.92^2 = 35.0464 \approx 35.04 \] So we have: \[ n(n + 2) = 35.04 \] 4. **Rearrange the Equation**: Rearranging gives us a quadratic equation: \[ n^2 + 2n - 35.04 = 0 \] For simplicity, we can approximate this to: \[ n^2 + 2n - 35 = 0 \] 5. **Factor the Quadratic Equation**: We need to factor the quadratic equation: \[ n^2 + 7n - 5n - 35 = 0 \] This can be factored as: \[ (n + 7)(n - 5) = 0 \] 6. **Solve for n**: Setting each factor to zero gives us: \[ n + 7 = 0 \quad \Rightarrow \quad n = -7 \quad (\text{not valid, as number of electrons cannot be negative}) \] \[ n - 5 = 0 \quad \Rightarrow \quad n = 5 \quad (\text{valid solution}) \] 7. **Conclusion**: The number of unpaired electrons present in the species is: \[ \boxed{5} \]
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