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Consider the equations given below and f...

Consider the equations given below and find the sum of x, y and z.
(i) `Mg+underset("(very dilute)")(xHNO_(3))(5%)rarrMg(NO_(3))_(2)+H_(2)`
(ii) `Cu+underset("(dil.)")(yHNO_(3))rarr 3Cu(NO_(3))_(2)+2NO+4H_(2)O`
(iii) `I_(2)+zHNO_(3)rarr 2HIO_(3)+10NO_(2)+4H_(2)O`

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To solve the problem, we need to balance the given chemical equations and find the values of \( x \), \( y \), and \( z \). Then, we will sum these values. ### Step 1: Balancing the first equation The first equation is: \[ \text{Mg} + x \text{HNO}_3 \rightarrow \text{Mg(NO}_3\text{)}_2 + \text{H}_2 \] 1. **Identify the products**: - Magnesium (Mg) is balanced on both sides (1 Mg). - In the product side, we have 2 nitrogen atoms (from \(\text{Mg(NO}_3\text{)}_2\)), which means we need 2 nitrogen atoms on the reactant side. Therefore, \( x \) must be 2 because each \(\text{HNO}_3\) contributes 1 nitrogen atom. - For oxygen, we have \( 2 \times 3 = 6 \) oxygen atoms on the product side, and with \( x = 2 \), we also have \( 2 \times 3 = 6 \) oxygen atoms on the reactant side. - Hydrogen: We have 2 hydrogen atoms from \( 2 \text{HNO}_3\) which matches the 2 hydrogen atoms from \( \text{H}_2\). Thus, \( x = 2 \). ### Step 2: Balancing the second equation The second equation is: \[ \text{Cu} + y \text{HNO}_3 \rightarrow 3 \text{Cu(NO}_3\text{)}_2 + 2 \text{NO} + 4 \text{H}_2\text{O} \] 1. **Identify the products**: - Copper (Cu): There are 3 Cu on the product side, so we need 3 Cu on the reactant side. - Nitrogen: From \( 3 \text{Cu(NO}_3\text{)}_2\), we have \( 3 \times 2 = 6 \) nitrogen atoms, and from \( 2 \text{NO}\), we have 2 nitrogen atoms, totaling 8 nitrogen atoms on the product side. Therefore, \( y \) must be 8 because \( y \) HNO3 contributes \( y \) nitrogen atoms. - Oxygen: From \( 3 \text{Cu(NO}_3\text{)}_2\), we have \( 3 \times 6 = 18 \) oxygen atoms, from \( 2 \text{NO}\) we have 2, and from \( 4 \text{H}_2\text{O}\) we have 4, totaling 24 oxygen atoms. With \( y = 8\), we have \( 8 \times 3 = 24\) oxygen atoms on the reactant side. - Hydrogen: We have \( 8 \) hydrogen atoms from \( 8 \text{HNO}_3\) which matches \( 4 \text{H}_2\text{O}\) (4 H). Thus, \( y = 8 \). ### Step 3: Balancing the third equation The third equation is: \[ \text{I}_2 + z \text{HNO}_3 \rightarrow 2 \text{HIO}_3 + 10 \text{NO}_2 + 4 \text{H}_2\text{O} \] 1. **Identify the products**: - Iodine: There are 2 iodine atoms on the product side, so we need 2 iodine atoms on the reactant side. - Nitrogen: From \( 10 \text{NO}_2\), we have 10 nitrogen atoms. Therefore, \( z \) must be 10 because \( z \) HNO3 contributes \( z \) nitrogen atoms. - Oxygen: From \( 2 \text{HIO}_3\), we have \( 2 \times 3 = 6\) oxygen atoms, from \( 10 \text{NO}_2\) we have \( 10 \times 2 = 20\), and from \( 4 \text{H}_2\text{O}\) we have 4, totaling 30 oxygen atoms. With \( z = 10\), we have \( 10 \times 3 = 30\) oxygen atoms on the reactant side. - Hydrogen: We have \( 2 \) from \( 2 \text{HIO}_3\) and \( 4 \) from \( 4 \text{H}_2\text{O}\), totaling 10 hydrogen atoms. With \( z = 10\), we have \( 10 \) hydrogen atoms on the reactant side. Thus, \( z = 10 \). ### Step 4: Calculate the sum of \( x \), \( y \), and \( z \) Now we can find the sum: \[ x + y + z = 2 + 8 + 10 = 20 \] ### Final Answer The sum of \( x \), \( y \), and \( z \) is \( 20 \).
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