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Identify (X), (Y) and (Z) in the given r...

Identify (X), (Y) and (Z) in the given reaction.
`CH_(3)COCH_(3) overset(I_(2)+NaOH)underset("heat") to X overset(Ag)underset("heat") to Y overset(H_(2)SO_(4)//HgSO_(4))underset("heat") to Z`

A

`X=CHI_(3), Y=CH_(3)CHO, Z=HCHO`

B

`X=CHI_(3), Y=CH_(3)OH, Z=CH_(3)CHO`

C

`X=CHI_(3), Y=CH-=CH, Z=CH_(3)CHO`

D

`X=CH_(3)COCl_(3), Y=CH_(2)=CH_(2), Z=CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step by step, we will identify the compounds (X), (Y), and (Z) in the reaction sequence provided. ### Step 1: Identify (X) The starting compound is **CH₃COCH₃** (acetone). When acetone is treated with **I₂** and **NaOH** under heat, it undergoes a reaction known as the iodoform reaction. This reaction leads to the formation of **CHI₃** (iodoform). **Reaction:** \[ \text{CH}_3COCH_3 \xrightarrow{I_2 + NaOH, \text{heat}} \text{CHI}_3 \] Thus, **(X) = CHI₃**. ### Step 2: Identify (Y) Next, the iodoform (CHI₃) is subjected to heat in the presence of **Ag**. In this reaction, the iodoform undergoes dehydrohalogenation, leading to the formation of an alkyne. The product formed is **C₂H₂** (ethyne), which can be represented as **CH≡CH**. **Reaction:** \[ \text{CHI}_3 \xrightarrow{Ag, \text{heat}} \text{CH} \equiv \text{CH} \] Thus, **(Y) = CH≡CH**. ### Step 3: Identify (Z) Finally, the alkyne (CH≡CH) undergoes oxymercuration followed by demercuration when treated with **H₂SO₄** and **HgSO₄** under heat. This reaction converts the alkyne into an aldehyde. The product formed is **CH₃CHO** (acetaldehyde). **Reaction:** \[ \text{CH} \equiv \text{CH} \xrightarrow{H_2SO_4/HgSO_4, \text{heat}} \text{CH}_3CHO \] Thus, **(Z) = CH₃CHO**. ### Summary of Identifications - **(X) = CHI₃** - **(Y) = CH≡CH** - **(Z) = CH₃CHO** ### Final Answer The final answer is: - **(X) = CHI₃** - **(Y) = CH≡CH** - **(Z) = CH₃CHO**
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