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Fill in the reagents for the given conve...

Fill in the reagents for the given conversion :
`CH_(3)COCl overset((X))to CH_(3)CHO overset((Y))to CH_(3)-overset(OH) overset(|)(CH)-CH_(2)CHO overset((Z))to CH_(3)CH=CHCHO`

A

`|{:(X,Y,Z),(Pd//BaSO_(4),"dil. NaOH","heat"):}|`

B

`|{:(X,Y,Z),("NaOH","Hydrolysis","heat"):}|`

C

`|{:(X,Y,Z),(I_(2)//NaOH,LiAlH_(4),H_(3)O^(+)):}|`

D

`|{:(X,Y,Z),(CrO_(3),"Warm",CO_(2)):}|`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given conversion step by step, we will identify the reagents needed for each transformation. ### Step 1: Conversion of CH₃COCl to CH₃CHO The first conversion is from acetyl chloride (CH₃COCl) to acetaldehyde (CH₃CHO). This transformation can be achieved using the reagent **Pd/BaSO₄**, which is a catalyst used in the Poisson's reaction. **Reagent X:** Pd/BaSO₄ ### Step 2: Conversion of CH₃CHO to CH₃-CHOH-CH₂CHO Next, we need to convert acetaldehyde (CH₃CHO) to a compound that has both an alcohol and an aldehyde functional group, specifically CH₃-CHOH-CH₂CHO. This can be done by treating the aldehyde with **NaOH** (sodium hydroxide), which will lead to the formation of a β-hydroxy aldehyde through an aldol reaction. **Reagent Y:** NaOH ### Step 3: Conversion of CH₃-CHOH-CH₂CHO to CH₃CH=CHCHO In the final step, we need to convert the β-hydroxy aldehyde (CH₃-CHOH-CH₂CHO) to an α,β-unsaturated aldehyde (CH₃CH=CHCHO). This can be accomplished by heating the compound, which will lead to dehydration (removal of water) and formation of the double bond. **Reagent Z:** Heat ### Summary of Reagents - **Reagent X:** Pd/BaSO₄ - **Reagent Y:** NaOH - **Reagent Z:** Heat ### Final Answer The complete sequence of reagents for the conversions is: - X: Pd/BaSO₄ - Y: NaOH - Z: Heat
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