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A cylinder closed at both ends is separa...

A cylinder closed at both ends is separated into two equal parts (45 cm each) by a piston impermeable to heat. Both the parts contain the same masses of gas at a temperature of 300 K and a pressure of 1 atm. If now the gas in one of parts is heated such that the piston shifts by 5 cm, then the temperature and the pressure of the gas in this part after heating is

A

T = 365 K and P = 1.125 atm

B

T = 350 K and P = 1.125 atm

C

T= 375 K and P = 2.125 atm

D

T = 375 K and P = 1.125 atm

Text Solution

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The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Understand the Initial Conditions We have a cylinder divided into two equal parts, each with a length of 45 cm. The gas in both parts has the same mass, pressure (1 atm), and temperature (300 K). - Volume of each part (initially) = \( V_1 = V_2 = 45 \times A \) (where A is the cross-sectional area) ### Step 2: Analyze the Heating Process When the gas in one part is heated, the piston shifts by 5 cm. This means: - New volume of the heated part (after heating) = \( V_1' = 50 \times A \) - New volume of the other part (compressed) = \( V_2' = 40 \times A \) ### Step 3: Apply the Ideal Gas Law The ideal gas law states: \[ PV = nRT \] Where: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = universal gas constant - \( T \) = temperature ### Step 4: Set Up Equations for the Final State Since the piston is impermeable to heat, the pressure in both chambers will be equal at equilibrium: \[ P_1' = P_2' \] Using the ideal gas law for both parts: 1. For the heated part: \[ P_1' \cdot V_1' = nR \cdot T_1' \] \[ P_1' \cdot (50A) = nR \cdot T_1' \] 2. For the other part: \[ P_2' \cdot V_2' = nR \cdot T_2 \] \[ P_2' \cdot (40A) = nR \cdot 300 \] ### Step 5: Equate Pressures Since \( P_1' = P_2' \): \[ P_1' = \frac{nR \cdot T_1'}{50A} \] \[ P_2' = \frac{nR \cdot 300}{40A} \] Setting these equal gives: \[ \frac{nR \cdot T_1'}{50A} = \frac{nR \cdot 300}{40A} \] ### Step 6: Simplify the Equation Cancel \( nR \) and \( A \) from both sides: \[ \frac{T_1'}{50} = \frac{300}{40} \] ### Step 7: Solve for \( T_1' \) Cross-multiplying gives: \[ 40T_1' = 300 \times 50 \] \[ T_1' = \frac{15000}{40} = 375 \, \text{K} \] ### Step 8: Calculate the Final Pressure Using the ideal gas law again for the heated part: \[ P_1' \cdot 50A = nR \cdot 375 \] Substituting \( nR \) from the other part: \[ P_1' \cdot 50A = \frac{nR \cdot 300}{40} \cdot 50 \] \[ P_1' = \frac{300 \cdot 50}{40 \cdot 50} = \frac{300}{40} = 7.5 \, \text{atm} \] ### Final Results Thus, the final temperature and pressure of the gas in the heated part are: - Temperature \( T_1' = 375 \, \text{K} \) - Pressure \( P_1' = 1.125 \, \text{atm} \)
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