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For the reaction A hArr B+C at equilibri...

For the reaction `A hArr B+C` at equilibrium, the concentration of A is `1xx10^(-3)M` B is 0.15 M and C is 0.05 M. The `DeltaG^(@)` for the hydrolysis of A at 300 K is `-X" kJ/mole"`. The value of X is ?
Report your answer by rounding it upto nearest integer.

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To solve the problem, we need to determine the value of \( X \) in the equation \( \Delta G^\circ = -X \) kJ/mol for the hydrolysis of \( A \) at 300 K. We will use the equilibrium concentrations given to find the equilibrium constant \( K_c \) and then relate it to \( \Delta G^\circ \). ### Step-by-Step Solution: 1. **Write the Reaction and Given Concentrations**: The reaction is: \[ A \rightleftharpoons B + C \] Given concentrations at equilibrium: - \([A] = 1 \times 10^{-3} \, \text{M}\) - \([B] = 0.15 \, \text{M}\) - \([C] = 0.05 \, \text{M}\) 2. **Calculate the Equilibrium Constant \( K_c \)**: The expression for the equilibrium constant \( K_c \) is: \[ K_c = \frac{[B][C]}{[A]} \] Substituting the given concentrations: \[ K_c = \frac{(0.15)(0.05)}{1 \times 10^{-3}} = \frac{0.0075}{0.001} = 7.5 \] 3. **Use the Relationship Between \( \Delta G^\circ \) and \( K_c \)**: The relationship is given by: \[ \Delta G^\circ = -RT \ln K_c \] Where: - \( R = 8.314 \, \text{J/mol·K} \) - \( T = 300 \, \text{K} \) 4. **Calculate \( \Delta G^\circ \)**: First, convert \( R \) to kJ: \[ R = 0.008314 \, \text{kJ/mol·K} \] Now, substituting the values: \[ \Delta G^\circ = - (0.008314)(300) \ln(7.5) \] 5. **Calculate \( \ln(7.5) \)**: Using a calculator: \[ \ln(7.5) \approx 2.014 \] 6. **Substituting Back to Find \( \Delta G^\circ \)**: \[ \Delta G^\circ = - (0.008314)(300)(2.014) \approx -5.02 \, \text{kJ/mol} \] 7. **Determine the Value of \( X \)**: Since \( \Delta G^\circ = -X \): \[ -X = -5.02 \implies X = 5.02 \] Rounding \( X \) to the nearest integer gives: \[ X \approx 5 \] ### Final Answer: The value of \( X \) is \( 5 \).
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