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Consider the following sequence of react...

Consider the following sequence of reaction and identify the final product (Z).
`CH_(3)CH_(2)CH_(2)Br overset("Mg dry ether")rarr (X) overset(CO_(2))rarr (Y) overset(H^(+))rarr(Z)`

A

`CH_(3)CH_(2)COOH`

B

`CH_(3)CH_(2)CH_(2)CH_(2)COOH`

C

`CH_(3)-underset(CH_(3))underset("| ")"CH"-COOH`

D

`CH_(3)CH_(2)CH_(2)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, let’s analyze the sequence of reactions provided: 1. **Starting Material**: The starting compound is 1-bromopropane (CH₃CH₂CH₂Br). 2. **Formation of Grignard Reagent (X)**: - When 1-bromopropane reacts with magnesium (Mg) in dry ether, it forms a Grignard reagent. - The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{Br} + \text{Mg} \xrightarrow{\text{dry ether}} \text{CH}_3\text{CH}_2\text{CH}_2\text{MgBr} \quad (X) \] - Here, (X) is the Grignard reagent, which is propylmagnesium bromide (CH₃CH₂CH₂MgBr). 3. **Reaction with Carbon Dioxide (Y)**: - The Grignard reagent (X) is then treated with carbon dioxide (CO₂). - The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{MgBr} + \text{CO}_2 \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{COO}^- + \text{MgBr}^+ \] - This results in the formation of a carboxylate ion (Y), which is propanoate ion (CH₃CH₂CH₂COO⁻). 4. **Protonation to form Final Product (Z)**: - The carboxylate ion (Y) is then treated with a proton source (H⁺), typically an acid. - The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{COO}^- + \text{H}^+ \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{COOH} \quad (Z) \] - This results in the formation of butanoic acid (CH₃CH₂CH₂COOH). Thus, the final product (Z) is butanoic acid. ### Final Answer: The final product (Z) is butanoic acid (CH₃CH₂CH₂COOH). ---
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