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CH3-overset(OH)overset(|)(CH)-overset(O)...

`CH_3-overset(OH)overset(|)(CH)-overset(O)overset(||)(C )-CH_2 - CH_(3)` will respond to

A

only Fehling solution

B

Only Tollen's reagent

C

Both Tollen's reagent and Fehling solution

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the organic molecule `CH3-overset(OH)overset(|)(CH)-overset(O)overset(||)(C)-CH2-CH3`, we need to analyze its structure and determine its reactivity with Tollens' reagent and Fehling's solution. ### Step-by-Step Solution: 1. **Identify the Structure**: The given molecule can be represented as: \[ CH_3 - C(OH) - C(=O) - CH_2 - CH_3 \] This indicates that we have a hydroxyl group (-OH) attached to a carbon that is also connected to a carbonyl group (C=O). 2. **Determine Functional Groups**: The molecule contains: - An alcohol group (-OH) which is attached to a carbon that is also adjacent to a carbonyl group (C=O). - This structure indicates that it is an alpha-hydroxy ketone. 3. **Classify the Alpha-Hydroxy Ketone**: An alpha-hydroxy ketone can undergo tautomerization to form an aldehyde. However, for the molecule to be classified as a terminal alpha-hydroxy ketone, it should have the hydroxyl group at the end of the carbon chain, which is not the case here. 4. **Tautomerization**: The molecule can undergo tautomerization, but since it is not a terminal alpha-hydroxy ketone, it will not form a stable aldehyde that can react with Tollens' reagent or Fehling's solution. 5. **Reactivity with Tollens' and Fehling's Tests**: - **Tollens' Reagent**: This reagent tests for aldehydes. Since the molecule does not form a stable aldehyde, it will not give a positive test. - **Fehling's Solution**: Similar to Tollens', this reagent also tests for aldehydes. Again, since there is no stable aldehyde formed, it will not give a positive test. 6. **Conclusion**: Since the molecule does not respond to either Tollens' reagent or Fehling's solution, the correct answer is **none of these**. ### Final Answer: **None of these** ---
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