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2DCDO overset(OH^(-))rarr [X] and [Y] ar...

`2DCDO overset(OH^(-))rarr [X] and [Y]` are

A

`DCOO^(-), D_(2)CHOH`

B

`HCOO^(-), CH_(3)OH`

C

`HCOO^(-), CD_(3)OH`

D

`DCOO^(-), CD_(3)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of 2 moles of D-C-D-O in the presence of hydroxide (OH^(-)), we need to identify the products X and Y formed in this reaction, which is a type of Cain-Zarro reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: - The reaction is identified as a Cain-Zarro reaction, which involves two moles of carbonyl compounds that do not have alpha-hydrogens. 2. **Understand the Reactants**: - The reactant is D-C-D-O, which is a deuterated carbonyl compound (D indicates deuterium, a hydrogen isotope). 3. **Presence of Hydroxide Ion**: - The presence of hydroxide (OH^(-)) indicates that the reaction will involve both oxidation and reduction processes. 4. **Oxidation Process**: - In the oxidation step, the carbonyl compound will be converted into a carboxylate ion. The general formula for a carboxylate ion derived from a carbonyl compound is RCOO^(-). In this case, it will be D-C(=O)O^(-). 5. **Reduction Process**: - In the reduction step, the carbonyl compound will be reduced to an alcohol. The product will typically be in the form of R-OH. Here, it will be D-C-OH (deuterated alcohol). 6. **Final Products**: - Therefore, the products of the reaction are: - Product X: Carboxylate ion (D-C(=O)O^(-)) - Product Y: Alcohol (D-C-OH) ### Conclusion: The products X and Y formed from the reaction of 2 moles of D-C-D-O in the presence of hydroxide are: - X: D-C(=O)O^(-) (Carboxylate ion) - Y: D-C-OH (Deuterated alcohol)
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