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A colourless organic compound gives bris...

A colourless organic compound gives brisk effervescence with a mixture of sodium nitrite and dil. `HCl`. It could be

A

Oxalic acid

B

Acetic acid

C

Urea

D

Glucose

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the organic compound that gives brisk effervescence when reacted with a mixture of sodium nitrite (NaNO2) and dilute hydrochloric acid (HCl). ### Step-by-Step Solution: 1. **Understanding the Reaction**: When sodium nitrite (NaNO2) is mixed with dilute hydrochloric acid (HCl), it generates nitrous acid (HNO2). The reaction can be represented as: \[ \text{NaNO}_2 + \text{HCl} \rightarrow \text{HNO}_2 + \text{NaCl} \] 2. **Identifying the Organic Compound**: The organic compound in question must be capable of reacting with nitrous acid (HNO2) to produce gases that cause brisk effervescence. A well-known compound that reacts with HNO2 is urea (H2NCONH2). 3. **Reaction of Urea with HNO2**: When urea reacts with nitrous acid, it undergoes decomposition, producing carbon dioxide (CO2), ammonia (NH3), water (H2O), and nitrogen gas (N2). The reaction can be summarized as: \[ \text{H}_2\text{NCONH}_2 + \text{HNO}_2 \rightarrow \text{CO}_2 + \text{NH}_3 + \text{H}_2\text{O} + \text{N}_2 \] The production of gases like CO2 and N2 is what leads to the brisk effervescence observed. 4. **Conclusion**: Based on the above reactions and the fact that urea is a colorless organic compound, we can conclude that the compound that gives brisk effervescence with a mixture of sodium nitrite and dilute HCl is urea. ### Final Answer: The colorless organic compound is **urea (H2NCONH2)**.
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