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Ph-CH2-C-=CHunderset(Y)overset(X)hArrPh-...

`Ph-CH_2-C-=CHunderset(Y)overset(X)hArrPh-C-=C-CH_3`.
The reagents X and Y respectively are

A

Lindlar catalyst , `NaNH_2`

B

`NaNH_2` and alc . KOH

C

Pt catalyst , Wilkison's catalyst

D

Alc. KOH and `NaNH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reagents X and Y that facilitate the transformation of the compound Ph-CH₂-C≡CH into Ph-C≡C-CH₃. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting compound is Ph-CH₂-C≡CH, which is a terminal alkyne (with a triple bond between the second and third carbon). 2. **Identify the Target Compound**: The target compound is Ph-C≡C-CH₃, which is a terminal alkyne with the triple bond between the first and second carbon atoms. 3. **Understand the Reaction Type**: The transformation from a terminal alkyne to another terminal alkyne indicates that we are likely dealing with an isomerization reaction. In this case, we are moving the position of the triple bond. 4. **Determine Reagent Y**: To facilitate the isomerization of the alkyne, we can use a strong base. One common reagent for this purpose is sodium amide (NaNH₂). This reagent can deprotonate the terminal alkyne and allow for the rearrangement of the triple bond. 5. **Determine Reagent X**: After the isomerization step, we need to ensure that the reaction can proceed in the desired direction. Alcoholic KOH is a suitable reagent for promoting the isomerization of alkynes. It can help in the formation of the internal alkyne from the terminal alkyne. 6. **Final Conclusion**: Therefore, the reagents X and Y respectively are: - X: Alcoholic KOH - Y: Sodium amide (NaNH₂) ### Final Answer: - X = Alcoholic KOH - Y = Sodium amide (NaNH₂)
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