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In a compound AB, electro negativity dif...

In a compound AB, electro negativity difference between A and B is 1.9. Atomic radius A and B are `4Å and 2Å` . The distance between A and atoms means `d_(A-B)`

A

`6.72Å`

B

`5.82Å`

C

`6.9Å`

D

`7.5Å`

Text Solution

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The correct Answer is:
To solve the problem, we will use the given information about the electronegativity difference and the atomic radii of elements A and B. The goal is to find the distance between the atoms A and B, denoted as \( d_{A-B} \). ### Step-by-Step Solution: 1. **Identify Given Values:** - Electronegativity difference (\( \Delta \chi \)) = 1.9 - Atomic radius of A (\( r_A \)) = 4 Å - Atomic radius of B (\( r_B \)) = 2 Å 2. **Use the Steveson Equation:** The distance between atoms A and B can be calculated using the Steveson equation: \[ d_{A-B} = r_A + r_B - 0.03 \times \Delta \chi \] 3. **Substitute the Known Values:** Plug in the values into the equation: \[ d_{A-B} = 4 \, \text{Å} + 2 \, \text{Å} - 0.03 \times 1.9 \] 4. **Calculate the Electronegativity Adjustment:** Calculate \( 0.03 \times 1.9 \): \[ 0.03 \times 1.9 = 0.057 \] 5. **Complete the Calculation:** Now substitute this back into the equation: \[ d_{A-B} = 4 + 2 - 0.057 = 6 - 0.057 = 5.943 \, \text{Å} \] 6. **Final Result:** The distance between atoms A and B is approximately: \[ d_{A-B} \approx 5.94 \, \text{Å} \] 7. **Select the Correct Option:** Based on the options provided, the closest option to 5.94 Å is approximately 5.82 Å, which is option B. ### Summary: The calculated distance \( d_{A-B} \) is approximately 5.94 Å, and the correct answer from the options given is option B.
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