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What product (s) is (are) obtained when ...

What product (s) is (are) obtained when 2 - bromobutane undergoes an elimination reaction with a strong base ?

A

Only 1 - butene

B

Only 2 - butene

C

1 - butene and 2 - butene , with more 1 - butene

D

1 - butene and 2 - butene , with more 2 - butene

Text Solution

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The correct Answer is:
To determine the products obtained when 2-bromobutane undergoes an elimination reaction with a strong base, we can follow these steps: ### Step 1: Identify the structure of 2-bromobutane 2-bromobutane is a four-carbon alkyl halide with a bromine atom attached to the second carbon. Its structure can be represented as follows: ``` CH3-CH-CH2-CH3 | Br ``` ### Step 2: Understand the elimination reaction An elimination reaction involves the removal of a leaving group (in this case, bromine) and a hydrogen atom from adjacent carbon atoms, leading to the formation of a double bond. A strong base, such as alcoholic KOH, is typically used to facilitate this reaction. ### Step 3: Identify the β-hydrogens In 2-bromobutane, the carbon atoms adjacent to the carbon bonded to bromine (the α-carbon) are the β-carbons. The β-carbons are the second and third carbons in the chain. ### Step 4: Determine the possible products When a strong base removes a hydrogen atom from a β-carbon, two possible alkenes can be formed: 1. **1-butene**: This product is formed when a hydrogen atom is removed from the β-carbon adjacent to the α-carbon (the first carbon). The structure is: ``` CH2=CH-CH2-CH3 ``` 2. **2-butene**: This product is formed when a hydrogen atom is removed from the other β-carbon (the third carbon). The structure is: ``` CH3-CH=CH-CH3 ``` ### Step 5: Analyze the stability of the products 2-butene is more stable than 1-butene due to the presence of more alkyl substituents around the double bond (it has more α-hydrogens). Therefore, 2-butene is the major product, while 1-butene is the minor product. ### Conclusion The products obtained from the elimination reaction of 2-bromobutane with a strong base are: - **1-butene** (minor product) - **2-butene** (major product) ### Final Answer 1-butene and 2-butene are the products obtained when 2-bromobutane undergoes an elimination reaction with a strong base. ---
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