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The chemical formula of Prussian blue i...

The chemical formula of Prussian blue is formed by the reaction of ferric ion and ferrocyanide is

A

`K_4[Fe(CN)_6]`

B

`Na_4[Fe(CN)_6]`

C

`Fe_4[Fe(CN)_6]_3`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the chemical formula of Prussian blue formed by the reaction of ferric ion and ferrocyanide, we can follow these steps: ### Step 1: Identify the ions involved - The ferric ion is represented as \( \text{Fe}^{3+} \). - The ferrocyanide ion is represented as \( \text{[Fe(CN)_6]}^{4-} \). ### Step 2: Write the reaction - When ferric ions react with ferrocyanide ions, the reaction can be represented as: \[ \text{Fe}^{3+} + \text{[Fe(CN)_6]}^{4-} \rightarrow \text{Prussian blue} \] ### Step 3: Determine the formula of Prussian blue - The product formed from the reaction of one ferric ion and one ferrocyanide ion is \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \). - This is because two ferrocyanide ions are needed to balance the three ferric ions, resulting in the formula: \[ \text{Fe}_3[\text{Fe(CN)}_6]_2 \] ### Step 4: Simplify the formula - The simplified formula for Prussian blue is often written as \( \text{Fe}_4[\text{Fe(CN)}_6] \) or \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \), but it is commonly referred to as \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \) in literature. ### Step 5: Conclusion - Therefore, the chemical formula of Prussian blue formed by the reaction of ferric ion and ferrocyanide is \( \text{Fe}_3[\text{Fe(CN)}_6]_2 \). ### Final Answer - The correct option is **C**.
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