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Two moles of an ideal gas with (C(P))/(C...

Two moles of an ideal gas with `(C_(P))/(C_(V))= (5)/(3)` are mixed with 3 moles of another ideal gas with `(C_(P))/(C_(V))= (4)/(3)`. The value of `(C_(P))/(C_(V))` for the mixture is

A

1.45

B

`1.50`

C

1.47

D

1.42

Text Solution

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The correct Answer is:
To find the value of \((C_{P})/(C_{V})\) for the mixture of two ideal gases, we can follow these steps: ### Step 1: Identify the given values We have two gases: - Gas 1: \(C_{P}/C_{V} = 5/3\) with \(n_1 = 2\) moles - Gas 2: \(C_{P}/C_{V} = 4/3\) with \(n_2 = 3\) moles ### Step 2: Calculate \(C_{V}\) for each gas Using the relation: \[ \frac{C_{P}}{C_{V}} = 1 + \frac{R}{C_{V}} \] For Gas 1: \[ 1 + \frac{R}{C_{V1}} = \frac{5}{3} \] \[ \frac{R}{C_{V1}} = \frac{5}{3} - 1 = \frac{2}{3} \] Thus, \[ C_{V1} = \frac{3R}{2} \] For Gas 2: \[ 1 + \frac{R}{C_{V2}} = \frac{4}{3} \] \[ \frac{R}{C_{V2}} = \frac{4}{3} - 1 = \frac{1}{3} \] Thus, \[ C_{V2} = 3R \] ### Step 3: Calculate the total \(C_{V}\) for the mixture The total \(C_{V}\) for the mixture can be calculated using the formula: \[ C_{V \text{ mixture}} = \frac{n_1 C_{V1} + n_2 C_{V2}}{n_1 + n_2} \] Substituting the values: \[ C_{V \text{ mixture}} = \frac{2 \cdot \frac{3R}{2} + 3 \cdot 3R}{2 + 3} \] Calculating this: \[ = \frac{3R + 9R}{5} = \frac{12R}{5} \] ### Step 4: Calculate \((C_{P})/(C_{V})\) for the mixture Using the relation: \[ \frac{C_{P}}{C_{V \text{ mixture}}} = 1 + \frac{R}{C_{V \text{ mixture}}} \] Substituting \(C_{V \text{ mixture}} = \frac{12R}{5}\): \[ \frac{C_{P}}{C_{V \text{ mixture}}} = 1 + \frac{R}{\frac{12R}{5}} = 1 + \frac{5}{12} \] Calculating this: \[ = 1 + 0.4167 = 1.4167 \approx 1.42 \] ### Final Answer Thus, the value of \((C_{P})/(C_{V})\) for the mixture is approximately \(1.42\). ---
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