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The shape of XeO2F2 molecule is...

The shape of `XeO_2F_2` molecule is

A

Square planar

B

See - Saw

C

Tetrahedral

D

Trigonal bipyramidal

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shape of the `XeO_2F_2` molecule, we can follow these steps: ### Step 1: Determine the Valence Electrons First, we need to calculate the total number of valence electrons in the molecule. Xenon (Xe) has 8 valence electrons, each oxygen (O) has 6, and each fluorine (F) has 7. Therefore, the total is: - Valence electrons from Xe: 8 - Valence electrons from 2 O: 2 × 6 = 12 - Valence electrons from 2 F: 2 × 7 = 14 Total = 8 + 12 + 14 = 34 valence electrons. ### Step 2: Draw the Lewis Structure Next, we draw the Lewis structure for `XeO_2F_2`. Xenon will be the central atom, bonded to two oxygen atoms with double bonds and two fluorine atoms with single bonds. - Place Xe in the center. - Connect Xe to two O atoms with double bonds. - Connect Xe to two F atoms with single bonds. ### Step 3: Count Lone Pairs After placing the bonds, we need to account for the remaining valence electrons. Each double bond uses 4 electrons (2 pairs), and each single bond uses 2 electrons (1 pair). - Total electrons used in bonds: - 2 double bonds (4 electrons each) = 8 electrons - 2 single bonds (2 electrons each) = 4 electrons - Total used = 8 + 4 = 12 electrons. Remaining electrons = 34 - 12 = 22 electrons. Since each oxygen already has 4 electrons (from the double bonds), we can place 4 lone pairs (8 electrons) on each oxygen. The remaining electrons will be placed on the xenon. ### Step 4: Determine the Geometry Now, we can determine the molecular geometry. The central atom (Xe) has: - 4 bonding pairs (2 double bonds and 2 single bonds) - 1 lone pair This gives us a total of 5 electron pairs around the xenon atom. According to VSEPR theory, 5 electron pairs result in a trigonal bipyramidal arrangement. However, the presence of a lone pair will distort this geometry. ### Step 5: Identify the Final Shape With one lone pair, the geometry will be distorted from trigonal bipyramidal to a seesaw shape. ### Conclusion Thus, the shape of the `XeO_2F_2` molecule is **seesaw**.
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