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Consider the following sequence of react...

Consider the following sequence of reaction
The final product (Q) is`Ph-NO_2overset(Sn//HCl)rarr(X)overset(NaNO_2//HCl)rarrPoverset(CuBr//HBr)rarr(Q)` The final product (Q) is

A

chlorbenzene

B

bromobenzene

C

benzyl bromide

D

benzyl chloride

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given sequence of reactions, we will break down each step and identify the final product (Q). ### Step-by-Step Solution: 1. **Starting Material**: The reaction begins with nitrophenol (Ph-NO2). - **Reaction**: Ph-NO2 + Sn/HCl → Ph-NH2 (Aniline) - **Explanation**: The nitro group (NO2) is reduced to an amino group (NH2) using tin (Sn) in hydrochloric acid (HCl). This converts nitrophenol to aniline. 2. **Formation of Diazonium Salt**: The next step involves the conversion of aniline to a diazonium salt. - **Reaction**: Ph-NH2 + NaNO2/HCl → Ph-N2+Cl- (Diazonium salt) - **Explanation**: Aniline reacts with sodium nitrite (NaNO2) in the presence of hydrochloric acid (HCl) to form a diazonium salt (Ph-N2+Cl-), which is compound P. 3. **Sandmeyer Reaction**: The diazonium salt undergoes a Sandmeyer reaction to form bromobenzene. - **Reaction**: Ph-N2+Cl- + CuBr/HBr → Ph-Br (Bromobenzene) - **Explanation**: The diazonium salt reacts with copper(I) bromide (CuBr) in the presence of hydrobromic acid (HBr) to replace the diazonium group with a bromine atom, yielding bromobenzene as the final product (Q). ### Final Product: The final product (Q) is **Bromobenzene (Ph-Br)**. ### Summary of Steps: - Step 1: Reduction of nitrophenol to aniline. - Step 2: Diazotization of aniline to form diazonium salt. - Step 3: Sandmeyer reaction to form bromobenzene.
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Knowledge Check

  • Consider the following sequence of reaction, The major final product (B) is :

    A
    `H_2 N - CH_2 - COOH`
    B
    `Ph-underset(NH_2)underset(|)CH-COOH`
    C
    `Ph-CH_2-overset(NH_2)overset(|)CH-COOH`
    D
    `PhCH_2-underset(NH_2)underset(|)overset(COOEt)overset(|)C-COOH`
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