Home
Class 12
CHEMISTRY
For an exothermic reaction , temperature...

For an exothermic reaction , temperature increase by `10^@C` , the equilibrium constant will

A

2 times

B

Same

C

1/2 times

D

4 times

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the effect of temperature increase on the equilibrium constant for an exothermic reaction, we can follow these steps: ### Step-by-Step Solution 1. **Understand the Reaction Type**: - We are dealing with an exothermic reaction, which means that heat is released during the reaction. The general form of such a reaction can be represented as: \[ A \rightleftharpoons B + \text{Heat} \] 2. **Effect of Temperature on Exothermic Reactions**: - According to Le Chatelier's Principle, if a system at equilibrium is subjected to a change in temperature, the equilibrium will shift in a direction that counteracts the change. For an exothermic reaction, increasing the temperature shifts the equilibrium to the left (towards the reactants). 3. **Change in Concentrations**: - When the equilibrium shifts to the left, the concentration of the reactants (A) will increase, while the concentration of the products (B) will decrease. 4. **Equilibrium Constant Expression**: - The equilibrium constant \( K \) for the reaction can be expressed as: \[ K = \frac{[B]^b}{[A]^a} \] - Here, \( [B] \) and \( [A] \) are the concentrations of the products and reactants, respectively, and \( a \) and \( b \) are their stoichiometric coefficients. 5. **Effect on Equilibrium Constant**: - Since the concentration of A increases (due to the shift to the left), and the concentration of B decreases, the value of \( K \) will decrease. This indicates an inverse relationship between temperature and the equilibrium constant for exothermic reactions. 6. **Conclusion**: - Therefore, when the temperature is increased by \( 10^\circ C \), the equilibrium constant \( K \) for the exothermic reaction will decrease. ### Final Answer: The equilibrium constant will decrease.
Promotional Banner

Similar Questions

Explore conceptually related problems

For an exothermic reaction, what happens to the equilibrium constant if temperature is increased?

For a given exothermic reaction , K_P and K_p' are the equilibrium constant at temperature T_1 and T_2 respectively .Assuming that heat of reaction is constant in temperature range between T_1 and T_2 , it is readly observed that

On doubling P and V at constant temperature, the equilibrium constant will

Van't Hoff's equation for a chemical reaction under equilibrium is given by standard reaction enthalpy at temperature T and K is the equilibrium constant . Predict how K will vary with temperature for an exothermic

Assertion : The equilibrium constant for the reverse reaction is equal to the inverse of the equilibrium constant for the forward reaction . Reason : The value of equilibrium constant is independent of initial concentrations of the reactants and products.

For a given reversible reaction at a fixed temperature, equilibrium constants K_(p) and K_(c) are related by ………

Assertion (A) : The value of K increases with increase in temperature in case of endothermic reaction Reason (R) : The increase in temperature shifts the equilibrium in the backward direction in case of exothermic reaction.

With increase in temperature generally the value of the equilibrium constant of endothermic reversible reaction

For the reaction, A+2B hArr C , the expession for equilibrium constant is

The rate of an exothermic reactions increases with increase in temperature.