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For the complex ML(2) stepwise formatio...

For the complex `ML_(2) ` stepwise formation constants for
`M+L hArr ML `
`ML+L hArr ML_(2)`
are 4 and 3 . Hence overcell stability constant for ` M +2L hArr ML_(2)` is

A

12

B

7

C

1.33

D

0.75

Text Solution

AI Generated Solution

The correct Answer is:
To find the overall stability constant (cumulative constant) for the complex formation reaction \( M + 2L \rightleftharpoons ML_2 \), we will use the stepwise formation constants provided. ### Step-by-Step Solution: 1. **Identify the Stepwise Formation Constants**: - The first step is the formation of \( ML \) from \( M \) and \( L \): \[ M + L \rightleftharpoons ML \] The formation constant for this reaction is given as \( K_1 = 4 \). - The second step is the formation of \( ML_2 \) from \( ML \) and \( L \): \[ ML + L \rightleftharpoons ML_2 \] The formation constant for this reaction is given as \( K_2 = 3 \). 2. **Write the Expression for the Overall Stability Constant**: - The overall stability constant \( \beta_{1,2} \) for the reaction \( M + 2L \rightleftharpoons ML_2 \) can be expressed as the product of the stepwise constants: \[ \beta_{1,2} = K_1 \times K_2 \] 3. **Substitute the Values of \( K_1 \) and \( K_2 \)**: - Substitute the values we have: \[ \beta_{1,2} = 4 \times 3 \] 4. **Calculate the Overall Stability Constant**: - Perform the multiplication: \[ \beta_{1,2} = 12 \] 5. **Conclusion**: - The overall stability constant for the reaction \( M + 2L \rightleftharpoons ML_2 \) is: \[ \beta_{1,2} = 12 \] ### Final Answer: The overall stability constant for \( M + 2L \rightleftharpoons ML_2 \) is **12**.
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