Home
Class 12
CHEMISTRY
Product formed in the following reaction...

Product formed in the following reaction is `CH_3CH_2CH(OH)CH_3overset(H_2SO_4)rarr`

A

`CH_3CH=CHCH_3` predominates

B

`CH_2=CHCH_2CH_3` predominates

C

Both are formed in equal amounts

D

The amount of production depends on the nature of catalyst

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product formed in the reaction of 2-degree alcohol (specifically, 2-butanol) in the presence of concentrated sulfuric acid (H₂SO₄), we can follow these steps: ### Step 1: Identify the Alcohol The given alcohol is 2-butanol, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CHOHCH}_3 \] ### Step 2: Understand the Role of Concentrated H₂SO₄ Concentrated sulfuric acid acts as a dehydrating agent. It will facilitate the removal of a water molecule (H₂O) from the alcohol, leading to the formation of a carbocation. ### Step 3: Protonation of the Alcohol When 2-butanol reacts with H₂SO₄, the hydroxyl group (-OH) of the alcohol gets protonated, forming a better leaving group (water): \[ \text{CH}_3\text{CH}_2\text{C(OH)}\text{H}_3 + \text{H}^+ \rightarrow \text{CH}_3\text{CH}_2\text{C(OH}_2^+)\text{H}_3 \] ### Step 4: Formation of Carbocation The protonated alcohol (oxonium ion) loses a water molecule, resulting in the formation of a carbocation: \[ \text{CH}_3\text{CH}_2\text{C(OH}_2^+)\text{H}_3 \rightarrow \text{CH}_3\text{CH}_2\text{C}^+\text{H}_3 + \text{H}_2\text{O} \] ### Step 5: Elimination to Form Alkenes The carbocation can undergo elimination to form alkenes. In this case, two possible alkenes can be formed: 1. But-1-ene (from the elimination of a hydrogen from the terminal carbon) 2. But-2-ene (from the elimination of a hydrogen from the middle carbon) ### Step 6: Determine the Major Product But-2-ene is more stable than but-1-ene due to hyperconjugation and the presence of more alkyl groups attached to the double bond. Therefore, but-2-ene will be the major product. ### Final Answer The product formed in the reaction is **but-2-ene**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

The major product formed in the following reaction is : CH_3CH = CHCH(CH_3)_2 overset(HBr)(to)

The major product of the following reaction is : CH_(3)CH=CHCO_(2)CH_(3)overset(LiAlH_(4))rarr

What will be product in the following reaction CH_(3)-CH_(2)-CH_(2)-CH_(3)overset(KMnO_(4))rarr ?

major product of the following reaction is : CH_(3)CH=CHCO_(2)CH_(3) overset("LiAIH"_(4))rarr

Consider the following reactions (1) (CH_3)_3"CC"H(OH)CH_3overset("conc".H_2SO_4)rarr (2) (CH_3)_2"CHCH(Br)CH_(3)overset(conc.KOH)rarr (3) (CH_3)_2"CHCH(Br)CH_(3)overset((CH_3)_3CO^(-) Koplus)rarr (4) (CH_3)_2underset( "OH ")underset(" | ")(C-CH_2)-CHOoverset(Delta)rarr Which of these reaction(s) will produce Saytzeff product?

The major product formed in the following reaction is CH_3-underset(H)underset(|)overset(CH_3)overset(|)C-CH_2Brunderset(CH_3OH)overset(CH_3O^(-))to

Write structures of the products of the following reactions: (i) CH_(3)-CH=CH_(2)overset(H_(2)O //H^(+))rarr (ii) (iii) CH_(3)-CH_(2)-underset(CH_(3))underset("| ")("C ")H-CHO overset(NaBH_(4))rarr

Complete the following equations : 2CH_3OH overset(Conc. H_2SO_4) rarr

The end product of the following reaction CH_(3)MgBr+CH_(2)=CH-CHOoverset(H_(3)O^(+))rarr is :

The major product formed in the following reation is CH_(3)-underset(H)underset(|)overset(CH_(3))overset(|)C-CH_(2)-Br underset(CH_(3)OH)overset(CH_(3)ONa)rarr .