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Which is not true above white phosphorus...

Which is not true above white phosphorus?

A

6 P - P single bods

B

4 P - P single bonds

C

4 long pair of electrons

D

P - P - P angle of `60^@`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "Which is not true about white phosphorus?" we need to analyze the properties and structure of white phosphorus (P4) and evaluate the given options. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Structure of White Phosphorus - White phosphorus consists of four phosphorus atoms arranged in a tetrahedral geometry. - The molecular formula is P4. **Hint:** Remember that the structure of white phosphorus is crucial for understanding its properties. ### Step 2: Analyze the Bonding - In white phosphorus, each phosphorus atom is bonded to three other phosphorus atoms through single bonds. - This results in a total of 6 P-P single bonds in the P4 molecule. **Hint:** Focus on the type of bonds and the number of bonds in the structure. ### Step 3: Determine the Bond Angles - The bond angles in white phosphorus are approximately 60 degrees due to its tetrahedral structure. **Hint:** Consider how the tetrahedral arrangement affects bond angles. ### Step 4: Count the Lone Pairs - Each phosphorus atom in white phosphorus has one lone pair of electrons, leading to a total of 4 lone pairs in the entire molecule. **Hint:** Remember that lone pairs can influence the reactivity and properties of the molecule. ### Step 5: Evaluate the Options - Now, we need to evaluate the provided options (A, B, C, D) to identify which statement is not true about white phosphorus based on our analysis. - After reviewing the properties: - 6 P-P single bonds: True - 4 lone pairs: True (1 lone pair per phosphorus atom) - P-P bond angle of 60 degrees: True - Any other statement that contradicts these facts would be the incorrect one. **Hint:** Compare each option against the established facts about white phosphorus. ### Conclusion After analyzing the structure, bonding, angles, and lone pairs of white phosphorus, we conclude that the statement in option B (or whichever option is identified as incorrect) is not true about white phosphorus. ### Final Answer The option that is not true about white phosphorus is **Option B**.
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