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The order of increasing reactivity of th...

The order of increasing reactivity of the following compounds towards HCl will be
(1) `CH_2=CH_2`
(2) `(CH_3)_2C=CH_2`
(3) `CH_3CH=CHCH_3`

A

`1 lt 2 lt 3`

B

`1 lt 3 lt 2`

C

`3 lt 2lt 1`

D

` 2 lt 1 lt 3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of increasing reactivity of the given compounds towards HCl, we will analyze each compound based on the stability of the carbocations formed during the reaction. ### Step-by-Step Solution: 1. **Identify the Compounds**: - Compound 1: Ethylene (CH₂=CH₂) - Compound 2: Isobutylene ((CH₃)₂C=CH₂) - Compound 3: 2-Butene (CH₃CH=CHCH₃) 2. **Understand the Reaction with HCl**: - When these alkenes react with HCl, the H⁺ ion from HCl will attack the double bond, leading to the formation of a carbocation intermediate. The stability of this carbocation is crucial for determining the reactivity of the alkene. 3. **Form the Carbocations**: - **For Compound 1 (CH₂=CH₂)**: - The reaction leads to the formation of a primary carbocation (C⁺), which is less stable. - **For Compound 2 ((CH₃)₂C=CH₂)**: - The reaction leads to the formation of a tertiary carbocation (C⁺), which is more stable than a primary carbocation. - **For Compound 3 (CH₃CH=CHCH₃)**: - The reaction leads to the formation of a secondary carbocation (C⁺), which is more stable than a primary but less stable than a tertiary. 4. **Evaluate Carbocation Stability**: - Stability order of carbocations: Tertiary (3°) > Secondary (2°) > Primary (1°). - Therefore: - Compound 1 forms a 1° carbocation (least stable). - Compound 2 forms a 3° carbocation (most stable). - Compound 3 forms a 2° carbocation (moderately stable). 5. **Determine Reactivity Order**: - Since the reactivity of the compounds towards HCl is directly related to the stability of the carbocations formed: - Compound 2 ((CH₃)₂C=CH₂) will be the most reactive. - Compound 3 (CH₃CH=CHCH₃) will be less reactive than Compound 2 but more reactive than Compound 1. - Compound 1 (CH₂=CH₂) will be the least reactive. 6. **Final Order of Increasing Reactivity**: - Therefore, the order of increasing reactivity towards HCl is: - CH₂=CH₂ < CH₃CH=CHCH₃ < (CH₃)₂C=CH₂. ### Conclusion: The order of increasing reactivity of the compounds towards HCl is: **CH₂=CH₂ < CH₃CH=CHCH₃ < (CH₃)₂C=CH₂**.
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