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If lamda1 " and " lamda2 are the wavelen...

If `lamda_1 " and " lamda_2` are the wavelengths of the first members of the Lyman and paschen series respectively, then `lamda_1/lamda_2` is equal to

A

(a)`1:3`

B

(b)`1:30`

C

(c)`7:50`

D

(d)`7:108`

Text Solution

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The correct Answer is:
To solve the problem of finding the ratio of the wavelengths \( \frac{\lambda_1}{\lambda_2} \) for the first members of the Lyman and Paschen series, we will follow these steps: ### Step 1: Understand the Series and Identify the Values - The Lyman series corresponds to transitions where the electron falls to the first energy level (n=1) from higher levels (n=2, 3, 4,...). - The first member of the Lyman series is the transition from n=2 to n=1. - The Paschen series corresponds to transitions where the electron falls to the third energy level (n=3) from higher levels (n=4, 5, 6,...). - The first member of the Paschen series is the transition from n=4 to n=3. ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength of the emitted photon during these transitions is given by: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant. ### Step 3: Calculate \( \lambda_1 \) for the Lyman Series For the first member of the Lyman series: - \( n_1 = 1 \) - \( n_2 = 2 \) Using the Rydberg formula: \[ \frac{1}{\lambda_1} = R \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \left( 1 - \frac{1}{4} \right) = R \left( \frac{3}{4} \right) \] Thus, we have: \[ \lambda_1 = \frac{4}{3R} \] ### Step 4: Calculate \( \lambda_2 \) for the Paschen Series For the first member of the Paschen series: - \( n_1 = 3 \) - \( n_2 = 4 \) Using the Rydberg formula: \[ \frac{1}{\lambda_2} = R \left( \frac{1}{3^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{9} - \frac{1}{16} \right) \] Finding a common denominator (144): \[ \frac{1}{\lambda_2} = R \left( \frac{16 - 9}{144} \right) = R \left( \frac{7}{144} \right) \] Thus, we have: \[ \lambda_2 = \frac{144}{7R} \] ### Step 5: Calculate the Ratio \( \frac{\lambda_1}{\lambda_2} \) Now we find the ratio of the two wavelengths: \[ \frac{\lambda_1}{\lambda_2} = \frac{\frac{4}{3R}}{\frac{144}{7R}} = \frac{4}{3R} \cdot \frac{7R}{144} \] The \( R \) cancels out: \[ \frac{\lambda_1}{\lambda_2} = \frac{4 \cdot 7}{3 \cdot 144} = \frac{28}{432} \] Simplifying \( \frac{28}{432} \): \[ \frac{28}{432} = \frac{7}{108} \] ### Final Answer Thus, the ratio \( \frac{\lambda_1}{\lambda_2} \) is: \[ \frac{\lambda_1}{\lambda_2} = \frac{7}{108} \]
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