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A monatomic gas expands at constant pres...

A monatomic gas expands at constant pressure on heating. The percentage of heat supplied that increases the internal energy of the gas and that is involed in the expansion is

A

`75%,25%`

B

`25%,75%`

C

`60%,40%`

D

`40%,60%`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the percentage of heat supplied that increases the internal energy of a monatomic gas and the percentage that is involved in the expansion when the gas expands at constant pressure. ### Step-by-Step Solution: 1. **Understand the Process**: - We have a monatomic gas expanding at constant pressure (isobaric process). - The heat supplied (Q) is used for two purposes: increasing the internal energy (ΔU) and doing work (W) during expansion. 2. **Work Done in Isobaric Process**: - The work done by the gas during expansion at constant pressure is given by: \[ W = P \Delta V \] - Using the ideal gas law, we can express this in terms of temperature: \[ W = nR \Delta T \] - Here, \( n \) is the number of moles, \( R \) is the universal gas constant, and \( \Delta T \) is the change in temperature. 3. **Change in Internal Energy**: - For an ideal gas, the change in internal energy is given by: \[ \Delta U = n C_v \Delta T \] - For a monatomic gas, the specific heat at constant volume \( C_v \) is: \[ C_v = \frac{3}{2} R \] 4. **Heat Supplied in Isobaric Process**: - The heat supplied at constant pressure is given by: \[ Q = n C_p \Delta T \] - For a monatomic gas, the specific heat at constant pressure \( C_p \) is: \[ C_p = \frac{5}{2} R \] 5. **Calculate the Ratios**: - Now, we need to find the ratios \( \frac{\Delta U}{Q} \) and \( \frac{W}{Q} \). - First, calculate \( \frac{\Delta U}{Q} \): \[ \frac{\Delta U}{Q} = \frac{n C_v \Delta T}{n C_p \Delta T} = \frac{C_v}{C_p} \] - Since \( C_v = \frac{3}{2} R \) and \( C_p = \frac{5}{2} R \): \[ \frac{\Delta U}{Q} = \frac{\frac{3}{2} R}{\frac{5}{2} R} = \frac{3}{5} \] - This means that 60% of the heat supplied increases the internal energy of the gas. 6. **Calculate \( \frac{W}{Q} \)**: - Now, calculate \( \frac{W}{Q} \): \[ \frac{W}{Q} = \frac{n R \Delta T}{n C_p \Delta T} = \frac{R}{C_p} \] - Substituting \( C_p = \frac{5}{2} R \): \[ \frac{W}{Q} = \frac{R}{\frac{5}{2} R} = \frac{2}{5} \] - This means that 40% of the heat supplied is involved in the expansion. ### Final Results: - Percentage of heat supplied that increases the internal energy: **60%** - Percentage of heat supplied that is involved in the expansion: **40%**
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