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The basic character of MgO , BaO, and Na...

The basic character of MgO , BaO, and `Na_2O` and FeO follow the order

A

`MgO lt FeO lt BaO lt Na_2O`

B

`FeO lt MgO lt Na_2O lt BaO`

C

`FeO lt MgO lt BaO lt Na_2O`

D

`Na_2O lt MgO lt FeO lt BaO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of basic character for the oxides MgO, BaO, Na2O, and FeO, we can follow these steps: ### Step-by-Step Solution: 1. **Understand Basic Character**: Basic character refers to the ability of an oxide to react with acids and form salts and water. Generally, basic character increases down a group in the periodic table and decreases across a period from left to right. 2. **Identify the Group and Period**: - **Na2O** (Sodium Oxide) comes from Group 1 (alkali metals). - **BaO** (Barium Oxide) comes from Group 2 (alkaline earth metals). - **MgO** (Magnesium Oxide) also comes from Group 2. - **FeO** (Iron(II) Oxide) comes from the transition metals. 3. **Analyze Trends**: - **From Left to Right**: Basic character decreases. For example, Na2O (from Group 1) is more basic than MgO (from Group 2). - **From Top to Bottom**: Basic character increases. Barium (Ba) is below Magnesium (Mg) in Group 2, so BaO is more basic than MgO. 4. **Rank the Oxides**: - **Na2O**: Highest basic character due to being from Group 1. - **BaO**: Next, as it is from Group 2 and below Mg. - **FeO**: Lower than BaO due to being a transition metal oxide. - **MgO**: Lowest basic character among these oxides. 5. **Final Order**: Based on the analysis, the order of basic character is: - **Na2O > BaO > FeO > MgO** ### Conclusion: The correct order of basic character for the oxides is: **Na2O > BaO > FeO > MgO**
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