Home
Class 12
CHEMISTRY
CH3-CH = CH2+NOCl rarrP, Identify the ad...

`CH_3-CH = CH_2+NOCl rarrP`, Identify the adduct.

A

`CH_3-underset(Cl)underset(|)(CH)-underset(NO)underset(|)(CH_2)`

B

`CH_3-underset(NO)underset(|)(CH)-underset(Cl)underset(|)(CH_2)`

C

`CH_3-CH_2-underset(Cl)underset(|)overset(NO)overset(|)(CH)`

D

`underset(Cl)underset(|)(CH_2)-CH_2-underset(NO)underset(|)(CH_2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction between CH₃-CH=CH₂ and NOCl to identify the adduct (product P), we can follow these steps: ### Step 1: Identify the Reactants The reactants are: - Propene (CH₃-CH=CH₂) - Nitrosyl chloride (NOCl) ### Step 2: Understand the Reaction Type This reaction is an example of an electrophilic addition reaction. In this type of reaction, an electrophile (in this case, NOCl) adds across the double bond of an alkene (propene). ### Step 3: Determine the Electrophile and Nucleophile In the reaction, the NOCl acts as an electrophile. The nitrogen in NOCl is positively charged, making it an electrophile that will attack the double bond of propene. ### Step 4: Apply Markovnikov's Rule According to Markovnikov's rule, when HX (where X is a halogen) adds to an alkene, the hydrogen atom will attach to the carbon with the most hydrogen atoms already (the least substituted carbon), while the halogen will attach to the more substituted carbon. In our case: - The double bond in propene is between the first and second carbon. - The first carbon (C1) has 3 hydrogen atoms (CH₃), and the second carbon (C2) has 1 hydrogen atom (CH). - Therefore, the chlorine (from NOCl) will attach to the more substituted carbon (C2). ### Step 5: Write the Product The product formed will have: - Chlorine attached to C2 (the more substituted carbon). - The nitrogen from NOCl will form a bond with the remaining carbon (C1) and will also have an oxygen connected to it. Thus, the product (P) can be represented as: - CH₃-CH(Cl)-CH₂-N=O ### Step 6: Identify the Correct Option Now, we can check the options provided in the question to find the correct representation of the product. Based on our analysis, the correct option should show chlorine attached to the second carbon. ### Final Answer: The adduct (product P) formed from the reaction of CH₃-CH=CH₂ and NOCl is CH₃-CH(Cl)-CH₂-N=O.
Promotional Banner

Similar Questions

Explore conceptually related problems

CH_(3)CH=CH_(2)+NOClrarrP Identify the product.

CH_(3)-CH=CH_(2)overset(NOCl)rarr Product, product is :

I. CH_(3) - CH_(2) - CH_(2) - CH_(2) - OH II. CH_(3) - CH_(2) - underset(OH)underset(|)(CH) - CH_(3) III. CH_(3) - underset(OH) underset(|)overset(CH_(3))overset(|)(C) - CH_(3) IV. CH_(3) - underset(CH_(3))underset(|)(CH) - CH_(2) - OH V. CH_(3) - CH_(2) - O - CH_(2) - CH_(3) VI. CH_(3) - O - CH_(2) - CH_(2) - CH_(3) VII. CH_(3) - O - underset(CH_(3))underset(|)(CH) - CH_(3) Identify the pair of compounds that represents chain isomerism

I. CH_(3) - CH_(2) - CH_(2) - CH_(2) - OH II. CH_(3) - CH_(2) - underset(OH)underset(|)(CH) - CH_(3) III. CH_(3) - underset(OH) underset(|)overset(CH_(3))overset(|)(C) - CH_(3) IV. CH_(3) - underset(CH_(3))underset(|)(CH) - CH_(2) - OH V. CH_(3) - CH_(2) - O - CH_(2) - CH_(3) VI. CH_(3) - O - CH_(2) - CH_(2) - CH_(3) VII. CH_(3) - O - underset(CH_(3))underset(|)(CH) - CH_(3) Identify the pairs of compounds that represents position isomerism.

I. CH_(3) - CH_(2) - CH_(2) - CH_(2) - OH II. CH_(3) - CH_(2) - underset(OH)underset(|)(CH) - CH_(3) III. CH_(3) - underset(OH) underset(|)overset(CH_(3))overset(|)(C) - CH_(3) IV. CH_(3) - underset(CH_(3))underset(|)(CH) - CH_(2) - OH V. CH_(3) - CH_(2) - O - CH_(2) - CH_(3) VI. CH_(3) - O - CH_(2) - CH_(2) - CH_(3) VII. CH_(3) - O - underset(CH_(3))underset(|)(CH) - CH_(3) Identify the pairs of compounds which are functional group isomers

Which of the following has an asymmetric carbon atom ? (a) CH_3 - CH_2 -CH_2Br (b) CH_3 - underset(Br) underset(|) overset(H) overset(|)C- underset(CH_3) underset(|) CH - CH_3 (c) CH_3 - cH_2 -underset(CH_3)underset(|) overset(Br) overset(|)C-CH_3 (d) CH_3 - underset(Br) underset(|) overset(|) overset(CH_3) overset(|) C- CH_2 -CH_2-CH_3

Arrange the following compounds in increasing order of S_(N^1) reactivity. ClCH_2 = CH CH_2CH_3, CH_3C (Cl) = CH CH_2 CH_3, CH_2 = CH CH_2 CH_2 Cl, CH_3CH = CH. CHCl CH_3 .