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M(OH)x has a K(sp) or 4xx10^(-9) and it...

`M(OH)_x` has a `K_(sp)` or `4xx10^(-9)` and its is solubility is `10^(-3)` M. The value of x is

A

4

B

1

C

3

D

2

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the value of \( x \) in the compound \( M(OH)_x \) given its solubility product \( K_{sp} \) and solubility. ### Step-by-Step Solution: 1. **Understand the Dissociation of the Compound**: The compound \( M(OH)_x \) dissociates in solution as follows: \[ M(OH)_x \rightleftharpoons M^{+} + x OH^{-} \] 2. **Identify the Solubility**: The solubility of the compound is given as \( 10^{-3} \, \text{M} \). This means that at equilibrium: - The concentration of \( M^{+} \) ions is \( 10^{-3} \, \text{M} \). - The concentration of \( OH^{-} \) ions is \( x \times 10^{-3} \, \text{M} \) (since there are \( x \) hydroxide ions produced for each formula unit of \( M(OH)_x \)). 3. **Write the Expression for \( K_{sp} \)**: The solubility product \( K_{sp} \) is defined as: \[ K_{sp} = [M^{+}][OH^{-}]^x \] Substituting the concentrations: \[ K_{sp} = (10^{-3})(x \times 10^{-3})^x \] 4. **Substitute the Given \( K_{sp} \)**: We know that \( K_{sp} = 4 \times 10^{-9} \). Therefore, we can write: \[ 4 \times 10^{-9} = (10^{-3})(x \times 10^{-3})^x \] 5. **Simplify the Equation**: This can be rewritten as: \[ 4 \times 10^{-9} = 10^{-3} \cdot (x^{x} \cdot 10^{-3x}) \] Simplifying further gives: \[ 4 \times 10^{-9} = x^{x} \cdot 10^{-3 - 3x} \] 6. **Rearranging the Equation**: We can rearrange this to find: \[ 4 \times 10^{-9} \cdot 10^{3 + 3x} = x^{x} \] This simplifies to: \[ 4 \cdot 10^{3 + 3x - 9} = x^{x} \] \[ 4 \cdot 10^{3x - 6} = x^{x} \] 7. **Finding the Value of \( x \)**: To solve for \( x \), we can compare the powers of 10. Let’s express \( 4 \) as \( 2^2 \): \[ 2^2 \cdot 10^{3x - 6} = x^{x} \] We can assume \( x = 2 \) and check: \[ 2^2 \cdot 10^{3(2) - 6} = 2^{2} \] This simplifies to: \[ 4 \cdot 10^{0} = 4 \] Thus, \( x = 2 \) satisfies the equation. ### Conclusion: The value of \( x \) is \( 2 \).
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