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Two gases A and B having the same temper...

Two gases A and B having the same temperature 'T' , Same pressure 'P' and same volume 'V' are mixed . If the temperature of mixture is unchanged and the volume occupied by it is `'V//2'` , then the pressure of the mixture will be

A

P/2

B

P

C

2P

D

4P

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will use the ideal gas law and the information provided about the gases A and B. ### Step-by-Step Solution: 1. **Understand the Ideal Gas Law**: The ideal gas law is given by the equation \( PV = nRT \), where: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = ideal gas constant - \( T \) = temperature 2. **Initial Conditions**: - Both gases A and B are at the same temperature \( T \), pressure \( P \), and volume \( V \). - Therefore, for gas A: \[ P_A V = n_A R T \] and for gas B: \[ P_B V = n_B R T \] - Since \( P_A = P_B = P \), we can say: \[ PV = n_A R T \quad \text{and} \quad PV = n_B R T \] 3. **Total Moles of the Mixture**: - Let the number of moles of gas A and gas B be \( n_A \) and \( n_B \) respectively. - The total number of moles in the mixture is: \[ n_{total} = n_A + n_B \] 4. **Volume of the Mixture**: - The volume occupied by the mixture is given as \( \frac{V}{2} \). 5. **Pressure of the Mixture**: - Using the ideal gas law for the mixture, we have: \[ P_{mixture} \cdot \frac{V}{2} = n_{total} R T \] 6. **Relate Moles to Pressure**: - Since both gases have the same pressure \( P \) and volume \( V \), we can express the total moles in terms of pressure: \[ n_A = \frac{PV}{RT} \quad \text{and} \quad n_B = \frac{PV}{RT} \] - Therefore, the total number of moles is: \[ n_{total} = n_A + n_B = \frac{PV}{RT} + \frac{PV}{RT} = \frac{2PV}{RT} \] 7. **Substituting Back**: - Substitute \( n_{total} \) back into the equation for the pressure of the mixture: \[ P_{mixture} \cdot \frac{V}{2} = \left(\frac{2PV}{RT}\right) R T \] - Simplifying this gives: \[ P_{mixture} \cdot \frac{V}{2} = 2PV \] 8. **Solving for \( P_{mixture} \)**: - Rearranging the equation: \[ P_{mixture} = \frac{2PV}{\frac{V}{2}} = 4P \] ### Final Answer: The pressure of the mixture will be \( 4P \).
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