Home
Class 12
CHEMISTRY
Consider the following sequence of react...

Consider the following sequence of reaction. Identify the final product (Y) `CH_3CH_2CH_3overset(Cl_2//hv)rarr(X)overset(aq.OH^(-))rarr(Y)`

A

propan -1 -ol

B

propan -2- ol

C

mixture of both propan -1-ol and propan - 2 - ol

D

ethanol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, let's break down the reactions involved: ### Step 1: Identify the Initial Compound The initial compound given is **propane**, which has the molecular formula **C₃H₈** or **CH₃CH₂CH₃**. ### Step 2: Chlorination of Propane When propane is treated with chlorine (Cl₂) in the presence of light (hv), a free radical halogenation reaction occurs. This process involves the following: - The chlorine molecule undergoes homolytic cleavage to form two chlorine radicals (Cl·). - These radicals can abstract hydrogen atoms from propane, leading to the formation of alkyl radicals. ### Step 3: Formation of Products In the case of propane, two types of radicals can be formed: 1. **Primary Radical**: CH₃CH₂CH₂· (from the abstraction of a hydrogen from the terminal carbon) 2. **Secondary Radical**: CH₃CH·CH₃ (from the abstraction of a hydrogen from the middle carbon) The secondary radical is more stable due to hyperconjugation and will be the major product. This leads to the formation of **2-chloropropane (CH₃CHClCH₃)** as the major product and **1-chloropropane (CH₃CH₂CH₂Cl)** as the minor product. ### Step 4: Reaction with Aqueous OH⁻ Next, the product mixture (containing both 1-chloropropane and 2-chloropropane) is treated with aqueous hydroxide ions (OH⁻). This leads to a nucleophilic substitution reaction: - The hydroxide ion can attack the carbon atom bonded to the chlorine atom, leading to the substitution of the chlorine atom with a hydroxyl group (OH). ### Step 5: Identify the Final Products 1. From **2-chloropropane**: - The hydroxide ion replaces the chlorine, yielding **2-propanol (CH₃CHOHCH₃)**. 2. From **1-chloropropane**: - The hydroxide ion replaces the chlorine, yielding **1-propanol (CH₃CH₂CH₂OH)**. ### Final Conclusion The final products (Y) are a mixture of **1-propanol (C₃H₈O)** and **2-propanol (C₃H₈O)**. ### Answer The final product (Y) is a mixture of **1-propanol and 2-propanol**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Consider the following sequence of reaction and identify the final product (Z). CH_3-CH=CH_2overset(HBr)rarr(X)overset(Aq.NaOH)rarr(Y)overset(NaOH+l_2)rarr(Z)

Consider the following sequence of reaction and identify the final product (Z). CH_3-CH=CH_2overset(HBr)(rarr)(P)overset(aq.NaOH)(rarr)(Q)underset(K_2Cr_2O_7//H^+)overset("oxidation")(rarr)(R )

Consider the following sequence of reaction and identify the final product (Z). CH_(3)CH_(2)CH_(2)Br overset("Mg dry ether")rarr (X) overset(CO_(2))rarr (Y) overset(H^(+))rarr(Z)

In the following sequence of reactions, identify the final product. Cyclopentance overset(Cl_2//hv)rarr(I)overset(alc.KOH,Delta)rarr(II) overset((i) O_3)rarr(III)

Identify the final product CH_(2) = CH_(2) overset (Cl_(2)//H_(2)O)to X overset(-aq.KOH) to Y

The 'Y' in the following sequence of reactions CH_3-underset(OH)underset(|)(CH)-CH_3overset(PBr_3)rarr(X)overset(aq. NaOH)rarr(Y) is

Consider the following sequence of reactions : C_6H_5CH_3overset(Cl_2)rarrp-ClC_6H_4CH_3overset(NBS)rarr(X) overset(Mg)rarr(Y)overset((i)"ethylene oxide")rarr(Z) Final product (Z) is

In the reaction sequence CH_3-CH_2-CH_2-Broverset(AgCN) rarr (X) overset (H_2O/ H^(+))rarr(Y) (Y) will be

The final product (Z) is the following sequence of reaction CH_3CH_2NH_2overset(HNO_2)rarr(X)overset(Socl_2)rarr(Y) " is " overset(NH_3)rarr(Z)

Identify the final product (Z) in the following sequence of reactions. CH_3NH_2overset(CH_3l" Excess")rarr(X) overset(AgOH)rarr(Y)overset(Delta)rarr(Z)+ CH_3OH