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The average value of rotational kinetic ...

The average value of rotational kinetic energy of one mole of oxygen gas at temperature T will be

A

RT

B

`3/2` RT

C

`5/2` RT

D

`1/2` RT

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The correct Answer is:
To find the average value of rotational kinetic energy of one mole of oxygen gas at temperature T, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Type of Gas**: Oxygen gas (O₂) is a diatomic molecule. 2. **Determine Degrees of Freedom**: For a diatomic gas, the degrees of freedom (f) can be categorized as: - Translational degrees of freedom: 3 (movement in x, y, z directions) - Rotational degrees of freedom: 2 (rotation about two axes) - Vibrational degrees of freedom: Typically not considered at room temperature for this calculation. Thus, the total degrees of freedom for a diatomic gas like oxygen is 5 (3 translational + 2 rotational). 3. **Use the Formula for Average Kinetic Energy**: The average kinetic energy (KE) per degree of freedom is given by: \[ KE = \frac{f}{2} RT \] where R is the universal gas constant and T is the absolute temperature. 4. **Substitute the Degrees of Freedom**: Since we are interested in the rotational kinetic energy, we will only consider the rotational degrees of freedom (f = 2): \[ KE_{rotational} = \frac{2}{2} RT = RT \] 5. **Conclusion**: Therefore, the average value of the rotational kinetic energy of one mole of oxygen gas at temperature T is: \[ KE_{rotational} = RT \] ### Final Answer: The average value of rotational kinetic energy of one mole of oxygen gas at temperature T is \( RT \).
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