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The energy required for transition in a ...

The energy required for transition in a Hydrogen atom from `1^(st)` energy level to the `2^(nd)` energy level is E. Then , which of the following transitions is possible for the same energy in Helium atom ?

A

`2 rarr3`

B

`2rarr4`

C

`1rarr2`

D

`1rarr3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding which transition in a Helium atom corresponds to the same energy \( E \) required for a transition from the first energy level to the second energy level in a Hydrogen atom, we can follow these steps: ### Step 1: Determine the Energy Transition in Hydrogen The energy levels of a hydrogen atom are given by the formula: \[ E_n = -\frac{Z^2 \cdot 13.6 \, \text{eV}}{n^2} \] For Hydrogen, \( Z = 1 \). The energy required for the transition from the first energy level (\( n_1 = 1 \)) to the second energy level (\( n_2 = 2 \)) is: \[ E = E_2 - E_1 = \left(-\frac{1^2 \cdot 13.6}{2^2}\right) - \left(-\frac{1^2 \cdot 13.6}{1^2}\right) \] Calculating this gives: \[ E = \left(-\frac{13.6}{4}\right) - \left(-13.6\right) = -3.4 + 13.6 = 10.2 \, \text{eV} \] ### Step 2: Determine the Energy Transition in Helium For Helium, \( Z = 2 \). The energy levels are given by: \[ E_n = -\frac{Z^2 \cdot 13.6 \, \text{eV}}{n^2} = -\frac{4 \cdot 13.6}{n^2} \] We want to find \( n_1 \) and \( n_2 \) such that the energy difference corresponds to \( E = 10.2 \, \text{eV} \). The energy required for a transition from \( n_1 \) to \( n_2 \) in Helium is: \[ E' = E_{n_2} - E_{n_1} = \left(-\frac{4 \cdot 13.6}{n_2^2}\right) - \left(-\frac{4 \cdot 13.6}{n_1^2}\right) \] This simplifies to: \[ E' = 4 \cdot 13.6 \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right) \] Setting \( E' = 10.2 \, \text{eV} \): \[ 4 \cdot 13.6 \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right) = 10.2 \] ### Step 3: Solve for \( n_1 \) and \( n_2 \) Rearranging gives: \[ \frac{1}{n_1^2} - \frac{1}{n_2^2} = \frac{10.2}{4 \cdot 13.6} \] Calculating the right side: \[ \frac{10.2}{54.4} = \frac{1}{5.333} \approx 0.1875 \] Assuming \( n_1 = 2 \) and \( n_2 = 4 \): \[ \frac{1}{2^2} - \frac{1}{4^2} = \frac{1}{4} - \frac{1}{16} = \frac{4}{16} - \frac{1}{16} = \frac{3}{16} \approx 0.1875 \] Thus, the transition from \( n_1 = 2 \) to \( n_2 = 4 \) in Helium corresponds to the same energy \( E \) as the transition from \( n_1 = 1 \) to \( n_2 = 2 \) in Hydrogen. ### Conclusion The possible transition in the Helium atom that corresponds to the same energy \( E \) is from the second energy level to the fourth energy level.
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