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In an ideal gas at temperature T , the a...

In an ideal gas at temperature T , the average force that a molecule applies on the walls of a closed container depends on `T "as" T^(q)` . A good estimate for q is :-

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To solve the problem, we need to determine how the average force that a molecule applies on the walls of a closed container depends on the temperature \( T \) in an ideal gas. We are looking for a relationship of the form \( F \propto T^q \) and need to estimate the value of \( q \). ### Step-by-Step Solution: 1. **Understanding Pressure in an Ideal Gas**: The average pressure \( P \) exerted by an ideal gas on the walls of a container is given by the formula: \[ P = \frac{1}{3} \frac{m n}{V} v_{\text{rms}}^2 \] where: - \( m \) is the mass of a gas molecule, - \( n \) is the number of molecules, - \( V \) is the volume of the container, - \( v_{\text{rms}} \) is the root mean square speed of the gas molecules. 2. **Relating Average Force to Pressure**: The average force \( F \) that the gas molecules apply on the walls can be expressed as: \[ F = P \cdot A \] where \( A \) is the area of the wall. Substituting the expression for pressure: \[ F = \left(\frac{1}{3} \frac{m n}{V} v_{\text{rms}}^2\right) \cdot A \] 3. **Substituting Volume**: The volume \( V \) can be expressed as \( V = A \cdot L \) (where \( L \) is the length of the container). Thus, we can rewrite the force as: \[ F = \frac{1}{3} \frac{m n}{A \cdot L} v_{\text{rms}}^2 \cdot A \] Simplifying this gives: \[ F = \frac{1}{3} \frac{m n}{L} v_{\text{rms}}^2 \] 4. **Relating \( v_{\text{rms}} \) to Temperature**: The root mean square speed \( v_{\text{rms}} \) is related to the temperature \( T \) by the equation: \[ v_{\text{rms}}^2 \propto T \] Therefore, we can say: \[ v_{\text{rms}}^2 = \frac{3k_B T}{m} \] where \( k_B \) is the Boltzmann constant. 5. **Substituting Back**: Substituting \( v_{\text{rms}}^2 \) back into the expression for force: \[ F \propto \frac{m n}{L} \cdot T \] Since \( m \), \( n \), and \( L \) are constants, we can conclude that: \[ F \propto T \] 6. **Finding \( q \)**: From the relationship \( F \propto T^q \), we find that: \[ q = 1 \] ### Final Answer: The value of \( q \) is \( 1 \).
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