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The average rms speed of molecules in a ...

The average rms speed of molecules in a sample of oxygen gas at 300 K is `484ms^(-1)`., respectively. The corresponding value at 600 K is nearly (assuming ideal gas behaviour)

A

`968ms^(-1)`

B

`986ms^(-1)`

C

`648ms^(-1)`

D

`684ms^(-1)`

Text Solution

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The correct Answer is:
To solve the problem of finding the average root mean square speed of oxygen gas at 600 K, given its speed at 300 K, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Relationship**: The root mean square (rms) speed of gas molecules is given by the formula: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the gas constant, \( T \) is the absolute temperature, and \( M \) is the molar mass of the gas. For an ideal gas, the rms speed is directly proportional to the square root of the temperature. 2. **Set Up the Proportionality**: Since \( v_{rms} \) is proportional to \( \sqrt{T} \), we can express the relationship between the rms speeds at two different temperatures as: \[ \frac{v_1}{v_2} = \sqrt{\frac{T_1}{T_2}} \] where \( v_1 \) is the rms speed at temperature \( T_1 \) and \( v_2 \) is the rms speed at temperature \( T_2 \). 3. **Plug in the Known Values**: From the problem, we have: - \( v_1 = 484 \, \text{m/s} \) (at \( T_1 = 300 \, \text{K} \)) - \( T_2 = 600 \, \text{K} \) We need to find \( v_2 \). 4. **Calculate the Ratio**: \[ \frac{484}{v_2} = \sqrt{\frac{300}{600}} \] Simplifying the right side: \[ \sqrt{\frac{300}{600}} = \sqrt{\frac{1}{2}} = \frac{1}{\sqrt{2}} \] 5. **Rearranging the Equation**: Now we can rearrange the equation to solve for \( v_2 \): \[ v_2 = 484 \cdot \sqrt{2} \] 6. **Calculate \( v_2 \)**: Now we need to calculate \( 484 \cdot \sqrt{2} \): \[ \sqrt{2} \approx 1.414 \] Therefore: \[ v_2 \approx 484 \cdot 1.414 \approx 684 \, \text{m/s} \] ### Final Answer: The average rms speed of the molecules in the sample of oxygen gas at 600 K is approximately **684 m/s**.
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