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The de-Broglie wavelength lambda(n)of th...

The de-Broglie wavelength `lambda_(n)`of the electron in the `n^(th)` orbit of hydrogen atom is

A

inversely to n

B

Proportional to `n^(2)`

C

Proportional to n

D

Inversely proportional to `n^(2)`

Text Solution

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The correct Answer is:
To find the de-Broglie wavelength \(\lambda_n\) of the electron in the \(n^{th}\) orbit of a hydrogen atom, we can follow these steps: ### Step 1: Understand the de-Broglie wavelength formula The de-Broglie wavelength \(\lambda\) is given by the formula: \[ \lambda = \frac{h}{p} \] where \(h\) is Planck's constant and \(p\) is the momentum of the electron. ### Step 2: Express momentum in terms of mass and velocity The momentum \(p\) of the electron can be expressed as: \[ p = mv \] where \(m\) is the mass of the electron and \(v\) is its velocity. ### Step 3: Determine the velocity of the electron in the \(n^{th}\) orbit For an electron in the \(n^{th}\) orbit of a hydrogen atom, the velocity \(v_n\) can be derived from the Bohr model. The velocity is given by: \[ v_n = \frac{2 \pi^2 m z}{n h} \cdot \frac{1}{4 \pi \epsilon_0} \] where \(z\) is the atomic number (which is 1 for hydrogen), \(n\) is the principal quantum number, and \(\epsilon_0\) is the permittivity of free space. ### Step 4: Analyze the relationship between wavelength and orbit number From the above expression, we can see that the velocity \(v_n\) is inversely proportional to \(n\): \[ v_n \propto \frac{1}{n} \] Since momentum \(p\) is directly proportional to velocity: \[ p \propto v_n \propto \frac{1}{n} \] This implies that: \[ \lambda \propto \frac{1}{p} \propto n \] ### Step 5: Conclusion Thus, we conclude that the de-Broglie wavelength \(\lambda_n\) of the electron in the \(n^{th}\) orbit of the hydrogen atom is directly proportional to \(n\): \[ \lambda_n \propto n \] ### Final Answer The de-Broglie wavelength \(\lambda_n\) of the electron in the \(n^{th}\) orbit of the hydrogen atom is proportional to \(n\). ---
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