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A gas is heated in such a way that its p...

A gas is heated in such a way that its pressure and volume both become double. Now by decreasing temperature, some of air molecules were introduced into the container to maintain the increased volume and pressure. Assuming `1//4^(th)` of the initial number of moles has been given for this purpose. By what fraction of temperature has been raised finally of initial absolute temperature.

A

4 times

B

`(16)/(5)` times

C

`(4)/(5)`times

D

`(1)/(5)`times

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will use the ideal gas law and the information provided in the question. ### Step 1: Understand the initial conditions Let the initial pressure, volume, and temperature of the gas be \( P_0 \), \( V_0 \), and \( T_0 \) respectively. According to the ideal gas law: \[ P_0 V_0 = n R T_0 \] ### Step 2: Determine the new conditions after heating After heating, both the pressure and volume are doubled: \[ P' = 2P_0 \quad \text{and} \quad V' = 2V_0 \] Let the new temperature after heating be \( T' \). Using the ideal gas law again: \[ P' V' = n R T' \] Substituting the new values: \[ (2P_0)(2V_0) = n R T' \] This simplifies to: \[ 4P_0 V_0 = n R T' \] ### Step 3: Relate the new temperature to the initial temperature From the initial condition, we have: \[ P_0 V_0 = n R T_0 \] Substituting this into the equation for \( T' \): \[ 4(n R T_0) = n R T' \] Dividing both sides by \( nR \): \[ T' = 4T_0 \] ### Step 4: Introduce additional moles of gas Now, we introduce \( \frac{1}{4} \) of the initial number of moles into the container. The new number of moles becomes: \[ n' = n + \frac{n}{4} = \frac{5n}{4} \] ### Step 5: Determine the new temperature after adding moles Let the new temperature after adding the moles be \( T'' \). The pressure and volume are maintained at \( 2P_0 \) and \( 2V_0 \): \[ P' V' = n' R T'' \] Substituting the values: \[ (2P_0)(2V_0) = \left(\frac{5n}{4}\right) R T'' \] This simplifies to: \[ 4P_0 V_0 = \left(\frac{5n}{4}\right) R T'' \] Using \( P_0 V_0 = n R T_0 \): \[ 4(n R T_0) = \left(\frac{5n}{4}\right) R T'' \] Dividing both sides by \( nR \): \[ 4T_0 = \frac{5}{4} T'' \] ### Step 6: Solve for \( T'' \) Multiplying both sides by 4: \[ 16T_0 = 5T'' \] Now, solving for \( T'' \): \[ T'' = \frac{16T_0}{5} \] ### Step 7: Find the fraction of the temperature raised The initial temperature is \( T_0 \) and the final temperature is \( T'' \): \[ \text{Fraction of temperature raised} = \frac{T'' - T_0}{T_0} = \frac{\frac{16T_0}{5} - T_0}{T_0} \] This simplifies to: \[ = \frac{\frac{16T_0}{5} - \frac{5T_0}{5}}{T_0} = \frac{\frac{11T_0}{5}}{T_0} = \frac{11}{5} \] ### Final Answer The fraction of the temperature raised finally from the initial absolute temperature is: \[ \frac{11}{5} \]
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