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A compound has the formula C2HCl2Br. The...

A compound has the formula `C_2HCl_2Br.` The number of non - identical structures that are possible is

A

one

B

two

C

three

D

four

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of non-identical structures (isomers) possible for the compound with the formula \( C_2HCl_2Br \), we can follow these steps: ### Step 1: Identify the Molecular Formula The molecular formula given is \( C_2HCl_2Br \). ### Step 2: Calculate the Degree of Unsaturation The degree of unsaturation (DU) can be calculated using the formula: \[ DU = C - \frac{H + X}{2} + \frac{N}{2} + 1 \] where: - \( C \) = number of carbon atoms - \( H \) = number of hydrogen atoms - \( X \) = number of halogens (Cl, Br) - \( N \) = number of nitrogen atoms For \( C_2HCl_2Br \): - \( C = 2 \) - \( H = 2 \) - \( X = 2 \) (1 Cl and 1 Br) - \( N = 0 \) Substituting these values into the formula: \[ DU = 2 - \frac{2 + 2}{2} + 0 + 1 = 2 - 2 + 1 = 1 \] Thus, the degree of unsaturation is 1, indicating that there is one double bond or one ring present. ### Step 3: Determine the Structure Since we have a degree of unsaturation of 1, we can deduce that the compound is likely an alkene with a carbon-carbon double bond. ### Step 4: Draw Possible Structures We can draw the structures based on the placement of the substituents (Cl and Br) around the double bond: 1. **Structure 1**: - \( C=C \) - Cl on one carbon and H on the other carbon, with Br on the same carbon as Cl. - Structure: \[ Cl - C = C - H \] (Br is on the other carbon) 2. **Structure 2**: - \( C=C \) - Cl on one carbon and Br on the other carbon, with H on the same carbon as Cl. - Structure: \[ Cl - C = C - Br \] 3. **Geometric Isomers**: - **Cis Isomer**: Both Cl atoms on the same side. - **Trans Isomer**: Cl atoms on opposite sides. - **Cis Structure**: \[ Cl - C = C - Cl \] (Br and H can be on the same carbon as Cl) - **Trans Structure**: \[ Cl - C = C - Br \] ### Step 5: Count Non-Identical Structures From the above analysis, we can summarize the non-identical structures: 1. Cl on one carbon, H on the other (with Br on the same carbon as Cl). 2. Cl on one carbon, Br on the other (with H on the same carbon as Cl). 3. Geometric isomers (Cis and Trans). Thus, we find that there are **three non-identical structures** possible for \( C_2HCl_2Br \). ### Final Answer The number of non-identical structures that are possible is **3**. ---
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