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The reaction of benzoyl chloride with ph...

The reaction of benzoyl chloride with phenol in presence of NaOH is called

A

Schotten - Baumann reaction

B

Bouveault - Blank reduction

C

Clemmensen reduction

D

Stephen's reduction

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The correct Answer is:
To solve the question regarding the reaction of benzoyl chloride with phenol in the presence of NaOH, we can break it down into the following steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are benzoyl chloride (C6H5COCl) and phenol (C6H5OH). 2. **Understand the Role of NaOH**: - Sodium hydroxide (NaOH) acts as a base in this reaction. It deprotonates the hydroxyl group (-OH) of phenol, making it a more reactive nucleophile. 3. **Nucleophilic Attack**: - The deprotonated phenol (now a phenoxide ion, C6H5O-) attacks the carbonyl carbon of benzoyl chloride. This is a nucleophilic substitution reaction where the nucleophile (phenoxide ion) attacks the electrophile (carbonyl carbon of benzoyl chloride). 4. **Formation of the Intermediate**: - The nucleophilic attack leads to the formation of a tetrahedral intermediate, which subsequently collapses. 5. **Elimination of HCl**: - The tetrahedral intermediate collapses, resulting in the elimination of hydrochloric acid (HCl) and forming the final product. 6. **Identify the Product**: - The product formed from this reaction is phenyl benzoate (C6H5COOC6H5). 7. **Name of the Reaction**: - This reaction is specifically known as the Schotten-Baumann reaction, which is a method for acylating phenols using acid chlorides in the presence of a base. ### Final Answer: The reaction of benzoyl chloride with phenol in the presence of NaOH is called the **Schotten-Baumann reaction**. ---
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Knowledge Check

  • Hydrogenation of benzoyl chloride in the presence of Pd on BaSO_(4) gives

    A
    Benzyl alcohol
    B
    Benzaldehyde
    C
    Benzoic acid
    D
    Phenol.
  • Hydrogenation of benzoyl chloride in the presence of Pd on BaSO_(4) gives

    A
    Benzyl alcohol
    B
    Benzaldehyde
    C
    Benzoic acid
    D
    Phenol.
  • Hydrogenation of benzoyl chloride in the presence of Pd on BaSO_(4) gives

    A
    Benzyl alcohol
    B
    Benzaldehyde
    C
    Benzoic acid
    D
    Phenol.
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