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When bromoethane is subjected to Wurtz r...

When bromoethane is subjected to Wurtz reaction, the hydrocarbon mixture so obtained consist of

A

butane only

B

butane and ethane

C

butane and ethene

D

butane , ethane and ethene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to understand the Wurtz reaction and how it applies to bromoethane. Here’s a step-by-step breakdown: ### Step 1: Understand the Wurtz Reaction The Wurtz reaction involves the coupling of alkyl halides in the presence of sodium metal to form higher alkanes. The general reaction can be represented as: \[ 2 R-X + 2 Na \rightarrow R-R + 2 NaX \] where \( R \) is the alkyl group and \( X \) is the halogen. ### Step 2: Identify the Reactants In this case, the reactant is bromoethane (C2H5Br), which can be represented as: \[ \text{C}_2\text{H}_5\text{Br} \] ### Step 3: Write the Reaction When bromoethane is subjected to the Wurtz reaction with sodium, the reaction can be written as: \[ 2 \text{C}_2\text{H}_5\text{Br} + 2 \text{Na} \rightarrow \text{C}_4\text{H}_{10} + 2 \text{NaBr} \] ### Step 4: Determine the Product The product formed from the reaction is butane (C4H10). This is because two molecules of bromoethane couple together to form a longer carbon chain. ### Step 5: Analyze the Result Since bromoethane is a symmetrical alkyl halide, the only product formed will be butane. There are no other isomers or products formed in this reaction. ### Conclusion Thus, when bromoethane is subjected to the Wurtz reaction, the hydrocarbon mixture obtained consists solely of butane. ### Final Answer The hydrocarbon mixture obtained consists of butane. ---
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Knowledge Check

  • Wurtz reaction using bromoethane yields

    A
    (i) 2-bromobutane
    B
    (ii) n-butane
    C
    (iii) iso-butane
    D
    (iv) ethane.
  • Ethyl iodide and n-propyl iodide are allowed to undergo Wurtz reaction. The alkane which will not be obtained in this reaction is :

    A
    butane
    B
    propane
    C
    pentane
    D
    hexane
  • Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is: 1. CH -= CH 2. CH_2 = CH_2 3. CH_3 - CH_3 4. CH_4

    A
    `CH -= CH`
    B
    `CH_2 = CH_2`
    C
    `CH_3 - CH_3`
    D
    `CH_4`
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