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The reaction , RNH2+CHCl3+underset(("Eth...

The reaction , `RNH_2+CHCl_3+underset(("Ethanolic"))(3KOH)rarrR-overset(+)N-=overset(-)C+ 3KCl+3H_2O` is called

A

Cope reaction

B

Curtius reaction

C

Hoffmann - brmamide reaction

D

Carbylamine reaction

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of primary amine with chloroform and potassium hydroxide, we will analyze the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the given reaction are: - RNH₂ (a primary amine) - CHCl₃ (chloroform) - 3 KOH (potassium hydroxide) 2. **Understand the Reaction Conditions**: The reaction is carried out in ethanolic conditions, which means that ethanol is the solvent used. This can influence the reaction pathway. 3. **Recognize the Products**: The products of the reaction are: - RNC (alkyl isocyanide) - 3 KCl (potassium chloride) - 3 H₂O (water) 4. **Determine the Type of Reaction**: The reaction involves the formation of an isocyanide from a primary amine. This transformation is characteristic of a specific type of reaction known as the carbylamine reaction. 5. **Final Conclusion**: Based on the analysis, the reaction of a primary amine with chloroform and potassium hydroxide leading to the formation of an isocyanide is called the **carbylamine reaction**. ### Final Answer: The reaction is called the **carbylamine reaction**. ---
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