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MnO(4)^(-) ions can be reduced in strong...

`MnO_(4)^(-)` ions can be reduced in strongly alkaline medium to give

A

`MnO_2`

B

`Mn^(2+)`

C

`MnO_4^(2-)`

D

`MnO_3^-`

Text Solution

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The correct Answer is:
To solve the question regarding the reduction of \( \text{MnO}_4^{-} \) ions in a strongly alkaline medium, we can break down the process step by step. ### Step 1: Identify the Reactants and Products In a strongly alkaline medium, \( \text{MnO}_4^{-} \) ions are reduced. The expected products of this reaction include manganese dioxide (\( \text{MnO}_2 \)), hydroxide ions (\( \text{OH}^- \)), and oxygen gas (\( \text{O}_2 \)). ### Step 2: Write the Unbalanced Reaction The unbalanced reaction can be written as: \[ \text{MnO}_4^{-} + \text{OH}^- \rightarrow \text{MnO}_2 + \text{O}_2 + \text{H}_2\text{O} \] ### Step 3: Balance the Reaction To balance the reaction, we need to ensure that the number of atoms of each element is the same on both sides. The balanced reaction is: \[ 2 \text{MnO}_4^{-} + 4 \text{OH}^- \rightarrow 2 \text{MnO}_2 + 2 \text{O}_2 + 2 \text{H}_2\text{O} \] ### Step 4: Determine the Oxidation States Next, we need to determine the oxidation states of manganese in the reactants and products: - In \( \text{MnO}_4^{-} \): - Let the oxidation state of Mn be \( x \). - The equation becomes: \( x + 4(-2) = -1 \) - Thus, \( x - 8 = -1 \) leading to \( x = +7 \). - In \( \text{MnO}_2 \): - Let the oxidation state of Mn be \( y \). - The equation becomes: \( y + 2(-2) = 0 \) - Thus, \( y - 4 = 0 \) leading to \( y = +4 \). ### Step 5: Analyze the Change in Oxidation State The manganese ion is reduced from an oxidation state of +7 in \( \text{MnO}_4^{-} \) to +4 in \( \text{MnO}_2 \). This indicates that the manganese is undergoing reduction. ### Conclusion The product formed when \( \text{MnO}_4^{-} \) ions are reduced in a strongly alkaline medium is \( \text{MnO}_2 \). ### Final Answer The correct answer is \( \text{MnO}_2 \). ---
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