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Aromatic aldehydes in the presence of cy...

Aromatic aldehydes in the presence of cyanide ion as catalyst, are converted to acyloins. This reaction is called

A

Perkin reaction

B

Cannizzaro reaction

C

Benzoin condensation

D

Claisen condensation

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To solve the question regarding the conversion of aromatic aldehydes to acyloins in the presence of cyanide ion as a catalyst, we can break it down into clear steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is an aromatic aldehyde, which can be represented as \( C_6H_5CHO \) (for example, benzaldehyde). 2. **Catalyst Involvement**: - The catalyst used in this reaction is the cyanide ion (\( CN^- \)). This is typically provided in the form of potassium cyanide (KCN) in an alcoholic solution. 3. **Understanding the Reaction**: - In the presence of the cyanide ion, the aromatic aldehyde undergoes a reaction known as benzoin condensation. This reaction involves the nucleophilic attack of the cyanide ion on the carbonyl carbon of the aldehyde. 4. **Formation of Acyloin**: - During the reaction, two molecules of the aromatic aldehyde react to form an acyloin. The general structure of an acyloin can be represented as \( C_6H_5C(OH)(C_6H_5)C=O \). 5. **Final Product**: - The final product of this reaction is benzoin, which has the structure \( C_6H_5C(OH)C(=O)C_6H_5 \). 6. **Naming the Reaction**: - The reaction where aromatic aldehydes are converted to acyloins in the presence of cyanide ion is specifically called **Benzoin Condensation**. ### Final Answer: The reaction of aromatic aldehydes in the presence of cyanide ion as a catalyst, converting them to acyloins, is called **Benzoin Condensation**.
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