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In the closest packing of is N atoms . T...

In the closest packing of is N atoms . There are

A

N' Tetrahedral voids and '2N' octahedral voids

B

2N' Tetrahedral voids and 'N' octahedral voids

C

2N' Tetrahedral voids and '2N' octahedral voids

D

N' Tetrahedral voids and 'N' octahedral voids

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of determining the number of tetrahedral and octahedral voids in a closest packing arrangement of N atoms, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Closest Packing**: In closest packing, atoms are arranged in a way that maximizes the number of atoms in a given volume. The two common types of closest packing are face-centered cubic (FCC) and hexagonal close packing (HCP). **Hint**: Closest packing arrangements can be visualized as layers of spheres stacked in a specific manner. 2. **Identifying Tetrahedral Voids**: In a closest packing arrangement, each atom can create tetrahedral voids. Each atom contributes to one tetrahedral void above it and one below it. Therefore, for N atoms, there will be a total of 2N tetrahedral voids. **Hint**: Remember that each layer of spheres contributes to voids in the layers above and below. 3. **Identifying Octahedral Voids**: Octahedral voids are formed by the arrangement of six atoms surrounding a central void. In a close-packed structure, for every N atoms, there is one octahedral void. Hence, the number of octahedral voids will be equal to N. **Hint**: Visualize the arrangement of spheres; the octahedral voids are located at the center of the arrangement of six surrounding spheres. 4. **Summarizing the Results**: From the analysis, we conclude that: - The number of tetrahedral voids = 2N - The number of octahedral voids = N 5. **Choosing the Correct Option**: Based on the derived values, we can evaluate the given options: - Option A: N tetrahedral voids and 2N octahedral voids (Incorrect) - Option B: 2N tetrahedral voids and N octahedral voids (Correct) - Option C: 2N tetrahedral voids and 2N octahedral voids (Incorrect) - Option D: N tetrahedral voids and N octahedral voids (Incorrect) Therefore, the correct answer is **Option B: 2N tetrahedral voids and N octahedral voids**. ### Final Answer: **2N tetrahedral voids and N octahedral voids.**
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