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In an isothermal expansion of one mole o...

In an isothermal expansion of one mole of an ideal gas against vacuum from 5 litre to 50 litre at 300 K, the quantity of heat absorbed by the gas is

A

zero

B

80 lit. Atm

C

1380 cal

D

`-1380 cal`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the quantity of heat absorbed by one mole of an ideal gas during an isothermal expansion against vacuum, we can follow these steps: ### Step 1: Understand the Conditions of the Problem - We have an isothermal expansion, which means the temperature remains constant (T = 300 K). - The gas expands from a volume of 5 liters to 50 liters against a vacuum. ### Step 2: Analyze the Work Done - In an isothermal expansion against a vacuum, the external pressure is zero. - The work done (W) by the gas during expansion can be calculated using the formula: \[ W = -P_{\text{ext}} \Delta V \] where \( P_{\text{ext}} \) is the external pressure and \( \Delta V \) is the change in volume. - Since \( P_{\text{ext}} = 0 \) (because it is against vacuum), the work done is: \[ W = -0 \cdot (50 - 5) = 0 \] ### Step 3: Apply the First Law of Thermodynamics - The First Law of Thermodynamics states: \[ \Delta U = Q - W \] where \( \Delta U \) is the change in internal energy, \( Q \) is the heat absorbed, and \( W \) is the work done. - For an ideal gas undergoing an isothermal process, the change in internal energy (\( \Delta U \)) is zero because the temperature is constant: \[ \Delta U = 0 \] ### Step 4: Substitute Values into the First Law Equation - Since \( \Delta U = 0 \) and \( W = 0 \), we can substitute these values into the First Law equation: \[ 0 = Q - 0 \] - This simplifies to: \[ Q = 0 \] ### Conclusion - Therefore, the quantity of heat absorbed by the gas during this isothermal expansion against vacuum is: \[ Q = 0 \] ### Final Answer The quantity of heat absorbed by the gas is **0 Joules**. ---
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