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In the reaction Bromine 3Br2 + 6 OH^(-...

In the reaction Bromine
`3Br_2 + 6 OH^(-) rarr 5 Br ^(-) + BrO_3^(-) + 3H_2O`

A

is reduced

B

is oxidized

C

disproportionates

D

disintegrates

Text Solution

AI Generated Solution

The correct Answer is:
To determine whether bromine is reduced, oxidized, disproportionated, or disintegrated in the given reaction, we need to analyze the oxidation states of bromine in the reactants and products. 1. **Identify the oxidation state of bromine in the reactants**: - In the reactants, bromine (Br₂) is in its elemental form, which means it has an oxidation state of 0. 2. **Identify the oxidation states of bromine in the products**: - In the products, we have two different forms of bromine: - **Br⁻**: The oxidation state of bromine here is -1 (since it has a negative charge). - **BrO₃⁻**: To find the oxidation state of bromine in this compound, we can set up the equation: - Let the oxidation state of bromine be \( x \). - The oxidation states of oxygen are -2. Since there are three oxygen atoms, the total contribution from oxygen is \( 3 \times (-2) = -6 \). - The overall charge of the bromate ion (BrO₃⁻) is -1. - Therefore, we can write the equation: \[ x - 6 = -1 \] - Solving for \( x \): \[ x = -1 + 6 = +5 \] - Thus, the oxidation state of bromine in BrO₃⁻ is +5. 3. **Determine the changes in oxidation states**: - Bromine changes from an oxidation state of 0 in Br₂ to -1 in Br⁻ (reduction). - Bromine also changes from an oxidation state of 0 in Br₂ to +5 in BrO₃⁻ (oxidation). 4. **Conclusion**: - Since bromine undergoes both reduction (from 0 to -1) and oxidation (from 0 to +5), it is undergoing a disproportionation reaction. In a disproportionation reaction, a single element is both oxidized and reduced. Thus, the correct answer is that bromine **disproportionates** in the given reaction.
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