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In the given reaction CH3-CH2-Broverset(...

In the given reaction `CH_3-CH_2-Broverset("Moist"Ag_2O)rarr[X]` [X] will be

A

Ethanol

B

Diethyl ether

C

Propane

D

Propyne

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction of ethyl bromide (CH₃-CH₂-Br) with moist Ag₂O, we will follow these steps: ### Step 1: Understanding the Reactants We start with ethyl bromide (CH₃-CH₂-Br) and moist silver oxide (Ag₂O). The term "moist" indicates that water is present, which will lead to the formation of silver hydroxide (AgOH). **Hint:** Identify the reactants and their states. Moist Ag₂O means it is in the presence of water. ### Step 2: Formation of Silver Hydroxide When Ag₂O is mixed with water, it dissociates to form silver hydroxide: \[ \text{Ag}_2\text{O} + \text{H}_2\text{O} \rightarrow 2 \text{AgOH} \] **Hint:** Recognize that moist Ag₂O produces AgOH, which is crucial for the reaction. ### Step 3: Reaction of Ethyl Bromide with Silver Hydroxide The ethyl bromide (CH₃-CH₂-Br) will react with silver hydroxide (AgOH). The bromine atom (Br) will leave as bromide ion (Br⁻), and a carbocation (ethyl cation, CH₃-CH₂⁺) will be formed: \[ \text{CH}_3\text{CH}_2\text{Br} + \text{AgOH} \rightarrow \text{CH}_3\text{CH}_2^+ + \text{Ag}^+ + \text{Br}^- \] **Hint:** Understand the mechanism of the reaction where the leaving group (Br) forms a carbocation. ### Step 4: Nucleophilic Attack by Hydroxide Ion The hydroxide ion (OH⁻) from the dissociation of AgOH will then attack the ethyl cation (CH₃-CH₂⁺) to form ethanol (CH₃-CH₂OH): \[ \text{CH}_3\text{CH}_2^+ + \text{OH}^- \rightarrow \text{CH}_3\text{CH}_2\text{OH} \] **Hint:** Recognize that the nucleophile (OH⁻) attacks the electrophile (ethyl cation) to form the alcohol. ### Step 5: Formation of Products The overall reaction produces ethanol (CH₃-CH₂OH) and silver bromide (AgBr) as by-products: \[ \text{CH}_3\text{CH}_2\text{Br} + \text{AgOH} \rightarrow \text{CH}_3\text{CH}_2\text{OH} + \text{AgBr} \] **Hint:** Identify the final products of the reaction, which include the desired alcohol and a salt. ### Conclusion The product [X] formed from the reaction of ethyl bromide with moist Ag₂O is ethanol (CH₃-CH₂OH). **Final Answer:** Ethanol (CH₃-CH₂OH)
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