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Which among the following reagents conve...

Which among the following reagents convert alkyl halide into alkane ?

A

`Bu_3SnH`

B

Na/dry ether

C

`R_2CuLi`

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reagents can convert alkyl halides into alkanes, we will analyze each reagent mentioned in the question step by step. ### Step 1: Understanding the Reagents 1. **Bu3SnH (Tributyltin Hydride)**: - This is a reducing agent that can reduce alkyl halides to alkanes. - When an alkyl halide (like bromocyclohexane) is treated with Bu3SnH in the presence of light, the halide is replaced by hydrogen, yielding the corresponding alkane (cyclohexane). **Hint**: Look for reducing agents that can replace halides with hydrogen. --- ### Step 2: Wurtz Reaction with Na in Dry Ether 2. **Na in Dry Ether**: - This reagent is involved in the Wurtz reaction. - In this reaction, alkyl halides react with sodium metal in dry ether to form alkanes. - The process involves the formation of an alkyl radical which then combines with another alkyl halide to form an alkane. **Hint**: Identify reactions that involve sodium and ether for alkyl halide transformations. --- ### Step 3: R2CuLi (Gilman Reagent) 3. **R2CuLi (Gilman Reagent)**: - This reagent is used in the Corey-House reaction. - It reacts with alkyl halides to form alkanes. - The mechanism involves the nucleophilic attack of the R2CuLi on the alkyl halide, displacing the halide and forming the alkane. **Hint**: Recognize reagents that facilitate nucleophilic substitutions to yield alkanes. --- ### Conclusion After analyzing all the reagents, we find that: - **Bu3SnH** reduces alkyl halides to alkanes. - **Na in Dry Ether** (Wurtz reaction) converts alkyl halides to alkanes. - **R2CuLi** (Corey-House reaction) also converts alkyl halides to alkanes. Thus, all three reagents can convert alkyl halides into alkanes. ### Final Answer: The correct answer is **option four: all of these**. ---
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