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Ph-CHO+Ph-CHOoverset(Na(2)[Fe(CO)(4)])ra...

`Ph-CHO+Ph-CHOoverset(Na_(2)[Fe(CO)_(4)])rarrPh-overset(O)overset("||")C-OCH_(2)-Ph` . This reaction is known as :

A

Claisen reaction

B

Tischenko reaction

C

Perkin reaction

D

Cannizzaro reaction

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of phenyl aldehyde (Ph-CHO) with sodium tetracarbonylferrate (Na2[Fe(CO)4]) and identify the name of the reaction, we can break it down into the following steps: ### Step 1: Identify the Reactants The reactants in the reaction are two moles of phenyl aldehyde (Ph-CHO) and sodium tetracarbonylferrate (Na2[Fe(CO)4]). ### Step 2: Understand the Role of the Lewis Acid Sodium tetracarbonylferrate acts as a Lewis acid in this reaction. A Lewis acid is a compound that can accept an electron pair from a donor molecule (Lewis base). In this case, the phenyl aldehyde acts as the Lewis base. ### Step 3: Mechanism of the Reaction 1. The Lewis acid (Na2[Fe(CO)4]) interacts with the carbonyl group of one of the phenyl aldehydes, facilitating the formation of a more reactive intermediate. 2. This intermediate can then react with another molecule of phenyl aldehyde. 3. The reaction leads to the formation of an ester. ### Step 4: Identify the Product The product formed from this reaction is phenyl C=O O-CH2-Ph, which is an ester. ### Step 5: Name the Reaction The reaction where two aldehydes react in the presence of a Lewis acid to form an ester is known as the T-Schenko reaction. ### Final Answer The name of the reaction is **T-Schenko reaction**. ---
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