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In the given reaction [C6H5-CH2-CH2-over...

In the given reaction `[C_6H_5-CH_2-CH_2-overset(o+)(N)(CH_3)_2-CH_2-CH_3]overset(Theta)(OH)overset(Delta)rarr` (X) as major product will be

A

`C_6H_5-CH=CH_2`

B

`CH_2=CH_2`

C

`C_6H_5-CH=CH-CH_3`

D

`CH_3-CH=CH-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the given compound and the reaction conditions to determine the major product formed. ### Step 1: Analyze the Given Compound The compound provided is: \[ C_6H_5-CH_2-CH_2-N(CH_3)_2-CH_2-CH_3 \] This can be represented as: - A benzene ring (C6H5) - A chain of carbon atoms with an amine group (N(CH3)2) attached. ### Step 2: Identify the Reaction Conditions The compound is treated with: - Hydroxide ions (OH⁻) - Heat (Δ) ### Step 3: Recognize the Type of Reaction The reaction is likely a **Hofmann elimination**, which typically involves the removal of a hydrogen atom and a leaving group (in this case, the amine group) to form an alkene. ### Step 4: Identify Possible Hydrogen Atoms for Elimination In Hofmann elimination, we look for hydrogen atoms that can be abstracted. The compound has two possible hydrogen atoms that can be eliminated: 1. The hydrogen on the carbon adjacent to the nitrogen (N(CH3)2). 2. The hydrogen on the carbon adjacent to the benzene ring. ### Step 5: Determine the Preferred Hydrogen for Elimination The preferred hydrogen for elimination is generally the one that leads to the least stable alkene. In this case: - The hydrogen adjacent to the nitrogen is sterically hindered due to the presence of the bulky dimethylamino group. - The hydrogen adjacent to the benzene ring is less hindered. Thus, the hydrogen adjacent to the nitrogen is preferred for abstraction. ### Step 6: Perform the Elimination Reaction When the preferred hydrogen is abstracted, the following occurs: - The nitrogen group leaves, and a double bond forms between the two carbon atoms. This results in the formation of: - Ethene (C2H4) - The remaining structure with the benzene ring and the nitrogen group. ### Step 7: Write the Major Product The major product of the reaction is: \[ \text{Ethene} + \text{C}_6\text{H}_5-CH_2-CH_2-N(CH_3)_2 \] ### Final Answer The major product (X) formed in the reaction is **Ethene**. ---
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